介孔二氧化硅纳米管复合材料的制备及其场发射性能

Cao Yong, Lei Wei, Zhang Xiaobing, Wang Baoping
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引用次数: 0

摘要

采用高选择性催化法制备了粒径可控的碳纳米管/介孔二氧化硅复合材料。用SEM和TEM对复合材料进行了表征。结果表明,纳米束的大小比纳米管直径或功函数的差异更能决定SWNT/介孔二氧化硅复合材料的场发射性能。证明了通过调整合成参数来调整SWNT发射体电性能的可能性。此外,本研究结果表明,制备的SWNT/介孔二氧化硅复合材料具有与纯化的纳米管样品相似或更好的场发射性能,尽管制备的SWNT/介孔二氧化硅复合材料发射表面的纳米管浓度远低于纯SWNT样品。所制备的材料具有良好的场发射效率,并且消除了任何净化过程,这使该材料成为一种有吸引力的场发射材料。因此,我们可以预见,在这项工作中提出的方法为形成纳米材料的双组分结构提供了一个解决方案
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Preparation and Field Emission Properties of Mesoporous Silica Nanotube-ecomposites Materials
Carbon nanotube/mesoporous silica composites with controlled diameter and bundle size have been synthesized by using highly selective catalytic method. The composites were characterized by SEM and TEM. Results suggest that the bundle size, rather than the nanotube diameter or differences in work function, is more important in determining the field emission properties of SWNT/mesoporous silica composites. The possibility of tailoring the electrical properties of SWNT emitters by adjusting the synthesis parameters has been demonstrated. In addition, the present results show that the as-produced SWNT/mesoporous silica composites have similar or better field emission properties than the purified nanotube samples, even though the concentration of nanotubes on the emitting surface of the as-produced was much lower than that in the pure SWNT sample. The good field emission efficiency of the as-produced material combined with the convenience of eliminating any purification process make this material an attractive field emitter. Thus we can anticipate that the method presented in this work offers a solution to forming the bi-component structure of nanomaterials
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