地下电力电缆的老化:物质从半导电层向绝缘层迁移

Q. Pelzer, L. Perrin, P. Notingher, X. Colin, M. Benhassine, A. Resmond, L. Flandin
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引用次数: 2

摘要

中压地下电缆在空气中老化,温度在70℃至140℃之间。采用差示扫描量热法(DSC)和傅里叶变换红外光谱(FTIR)等物化技术对交联聚乙烯(XLPE)保温层结构性能的变化进行了表征。所进行的分析揭示了化学老化(氧化、添加剂的化学消耗、后交联……)和物理老化(化学物质的迁移)。对剥离XLPE样品的加速热测试表明,正如预期的那样,有轻微的氧化降解。相比之下,在存在半导电层的情况下进行的老化测试显示出显著的差异,额外的羰基物质迁移到XLPE绝缘中。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Ageing of underground power cables: species migration from semi-conductive layers to the insulating layer
Medium voltage underground cables were aged in air at temperatures between 70°C to 140°C. The changes of the structural properties of the crosslinked polyethylene (XLPE) insulating layer were characterized by physico-chemical techniques: Differential Scanning Calorimetry (DSC) and Fourier Transform Infrared Spectroscopy (FTIR). The performed analyses revealed chemical ageing (oxidation, chemical consumption of additives, post-crosslinking...) and physical ageing (migration of chemical species). The accelerated thermal tests on stripped XLPE samples showed, as expected, a mild oxidative degradation. In contrast, ageing tests conducted in the presence of the semi-conductive layers revealed a striking difference, with a migration of extra carbonyl species into the XLPE insulation.
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