纳米材料

Bionanotechnology Pub Date : 2021-02-04 DOI:10.5772/1371

이 익모, 진 인주

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引用次数: 323

摘要

本文研究了茂金属填充单壁碳纳米管(SWCNTs)的生长机理、结构、生长过程、生长动力学以及光学、振动和电子性能。提供了用于填充纳米管的程序的描述。采用拉曼光谱、近边缘x射线吸收精细结构光谱、光电发射光谱和光学吸收光谱等方法研究了金属丰度混合的茂金属填充SWCNTs的掺杂效应。讨论了掺杂对金属丰度分选的茂金属填充SWCNTs的影响。分析了掺杂对金属丰度混合和分选SWCNTs包被分子化学转化的影响。讨论了改性填充SWCNTs的电子性能。茂金属填充的SWCNTs在电化学、热电发电、化学传感器中的应用

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Nanomaterials

: In this paper, the growth mechanism, structure, growth processes, growth kinetics, and optical, vibronic and electronic properties of metallocene-ﬁlled single-walled carbon nanotubes (SWCNTs) are considered. A description of the procedures used to ﬁll the nanotubes is provided. An investigation of doping effects on metallicity-mixed SWCNTs ﬁlled with metallocenes by Raman spectroscopy, near edge X-ray absorption ﬁne structure spectroscopy, photoemission spectroscopy, and optical absorption spectroscopy is described. The studies of doping effects on metallicity-sorted SWCNTs ﬁlled with metallocenes are discussed. Doping effects in metallicity-mixed and sorted SWCNTs upon the chemical transformation of encapsulated molecules are analyzed. A discussion of the modiﬁcation of the electronic properties of ﬁlled SWCNTs is presented. Applications of metallocene-ﬁlled SWCNTs in electrochemistry, thermoelectric power generation, chemical sensors

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Bionanotechnology

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