用于监测海洋和沿海环境的MiniFluo-UV传感器的性能

M. Goutx, C. Bachet, N. Ferretto, C. Germain, C. Guigue, M. Tedetti
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引用次数: 1

摘要

了解海洋的生物地球化学功能需要DOM(溶解有机物)描述符的高频记录,这是色谱等传统工具无法提供的。十年来,荧光传感器的技术发展试图满足这一需求。实际上,光学特性允许正确地表征DOM,并且可以在高频下获得。在这种情况下,我们的实验室开发了MiniFluo-UV传感器,这是一种用于检测在紫外域发出荧光的芳香族化合物的小型化潜水荧光计的原型。传感器的质量包括漂移测量、线性、重复性、对光、温度和压力的敏感性以及标准溶液中菲和色氨酸的定量检出限。通过比较MiniFluo和不同荧光仪对原油WSF中菲浓度的测量结果进行了验证。在本次演示中,我们展示了MiniFluo-UV传感器在两个不同区域的部署结果,1)在狮子湾(DEWEX巡航,2013年冬季和春季)持续监测地中海西北部表层水层期间,2)受城市活动严重影响的马赛湾沿海海洋区域。原始计数的模式能够区分与狮子湾水文特征和春季生物生产相关的DOM的有趣分布。它还揭示了在人为压力下海洋地区污染物的积累。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Performance of the MiniFluo-UV sensor for monitoring ocean and coastal environments
Understanding the biogeochemical functioning of the ocean requires high frequency recordings of DOM (Dissolved Organic Matter) descriptors that traditional tools such chromatography cannot provide. For 10 years, the technological developments of fluorescence sensor try to cover this need. Indeed, optical properties allow to properly characterizing DOM and can be acquired at high frequency. In this context, our laboratory developed the MiniFluo-UV sensor, a prototype of miniaturized submersible fluorometers for the detection of aromatic compounds that fluoresce in the UV domain. The qualification of the sensor consisted of measurement of drift, linearity, repeatability, sensitivity to light, temperature and pressure, and detection limits of quantification of phenanthrene and tryptophan in standard solution. Validation was made by comparing measurements of phenanthrene concentrations in crude oil WSF by means of the MiniFluo and different fluorimeters. In this presentation, we show results of deployments of this MiniFluo-UV sensor in two distinct areas, 1) the North Western Mediterranean during the continuous monitoring of the surface water layer in the Gulf of Lion (DEWEX cruise, winter and spring 2013) and 2) the coastal marine area of Marseille bay heavily impacted by urban activities. The pattern of raw counts enabled to distinguish interesting distributions of DOM in relation to hydrological features and spring biological production in the Gulf of Lion. It also revealed accumulations of contaminants in marine areas under anthropic pressure.
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