纳米二氧化硅在水泥水化过程中的研究

Jon S. Belkowitz
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引用次数: 71

摘要

随着纳米技术的出现,已经开发出可以应用于高性能混凝土配合比设计的材料。纳米二氧化硅与氢氧化钙(CH)反应,形成更多的水泥承载强度结构:水合二氧化钙(CSH)。本文建立了不同粒径纳米二氧化硅在水泥浆体中的应用效果关系。为了确定纳米二氧化硅的效果,进行了广泛的实验分析。通过这些试验,测量了多种水泥配合比的水化热。然后通过x射线衍射记录CH的浓度。然后用扫描电子显微镜观察晶粒结构。最后,确定了每种水泥浆料的抗压强度。通过这些实验发现,随着硅颗粒尺寸的减小和尺寸分布的拓宽,CSHs变得更加刚性;这增加了抗压强度。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
The Investigation of Nano Silica in the Cement Hydration Process
With the advent of nano technology, materials have been developed that can be applied to high performance concrete mix designs. Nano silica reacts with calcium hydroxide (CH) to develop more of the strength carrying structure of cement: calcium silica hydrate (CSH). In this paper, relationships have been developed to distinguish the benefits when using different sizes of nano silica in cement paste. An extensive regime of experimental analysis was carried out to determine the effect of nano silica. Through these experiments the heat of hydration of multiple cement mix designs was measured. After that, the concentration of CH was recorded through X-ray diffraction. Then, the grain structures were examined through Scanning Electron Microscopy. Finally, the compressive strength was determined for each cement paste mixture. Through these experiments it was found that as the silica particles decreased in size and their size distribution broadened, the CSHs became more rigid; this increased the compressive strength.
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