微型生物燃料电池输出功率与正极材料类型的关系

A. V. Pudova, I. Mandrik, Aliaksandra D. Kolesova, T. M. Zimina, D. Snarskaya
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摘要

对可再生燃料的需求使得开发基于蓝藻的生物燃料电池变得非常重要。在之前的工作中,我们发现在胞杆菌菌株中,聚藻球菌比水藻球菌更有效,混合碳阳极的最高效率为~2 mW/m2。在这项工作中,我们测试了一些混合碳阳极,包括碳毡和碳面纱。通过对所使用的各种碳的分析和测试,得出了使用碳毡作为阳极的最高功率输出为10 mW/m2。这可以解释为,与其他材料相比,这种材料具有较大的表面积体积比和孔隙率,这是蓝藻生物膜产生和生长的有利因素。得到一个电池的输出功率后,对理想条件下8个电池组成的矩阵的功率进行了理论计算。该电池的功率约为4 μW,是普通电池的2.7倍。这个计算是理论上的,因此在实践中,由于生物体的不可预测性,这个功率可能会略有不同。这样做的基本原理是,连接多个生物设备可能比连接传统电池或超级电容器要困难得多,因为存储设备之间的阻抗不匹配可能会导致显著的性能下降。可能的大电压降主要是由于单个单元的性能分布不均匀以及随后来自效率较低的电池的电压反转。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Output Power of Miniature Bio Fuel Cell versus Anode and Cathode Material Type
The need for renewable fuel sources make it important to develop biofuel cells based on cyanobacteria. In the previous work we found out that among cyaqnobacteria strains Synechococcus was more effective than Anabaena, and maximum efficiency with hybrid carbon anode was ~2 mW/m2. In this work we tested a number of hybrid carbon anodes including carbon felt and carbon veil. After analyzing and testing all the types of carbon used, it was concluded that the highest power output of 10 mW/m2 was achieved using carbon felt as the anode. This can be explained by the fact that this material, in comparison with the others, has a large surface area to volume ratio and porosity, which is a favorable factor for the creation and growth of cyanobacterial biofilms. Having received the output power of one cell, a theoretical calculation was made of the power of the matrix of 8 cells under ideal conditions. This power was about 4 μW, which is 2.7 times higher than the power of one such cell. This calculation is theoretical, so it is likely that in practice, due to the unpredictability of living organisms, this power will be slightly different. The rationale for this is that connecting multiple biological devices can be much more difficult than connecting conventional batteries or supercapacitors, because there is the potential for significant performance degradation due to varying impedance mismatches between stored devices. The possible large voltage drop is mainly due to the uneven distribution of the performance of individual units and the subsequent voltage reversal from the less efficient cells.
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