核壳静电纺丝同步修饰TiO2复合纳米纤维表面

Hao Peng, Guoyi Kang, Jiaxin Jiang, Zungui Shao, Juan Liu, Yifang Liu, G. Zheng
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引用次数: 0

摘要

提出了一种基于核-壳静电纺丝的在线表面改性工艺,用于制备功能复合纳米纤维。将聚乙烯氧化物(PEO)溶液和二氧化钛(TiO2)悬浮液分别通过喷丝板的芯道和壳道提供,得到PEO/TiO2复合纳米纤维。将PEO溶液拉伸固化成纳米纤维,并将TiO2纳米粒子嵌入PEO纳米纤维中。该方法为提高纳米纤维表面功能纳米粒子的分布比例提供了良好的途径。利用x射线衍射和傅里叶变换红外光谱对复合纳米纤维的材料成分进行了确定。经核-壳静电纺丝,钛的质量含量可达3.81 wt%。PEO/TiO2纳米纤维增强了其抗紫外线功能。本工作证明了同轴静电纺丝在静电纺丝过程中对纤维表面进行改性的可能性和有效性,为制备复合纳米纤维材料提供了进一步的思路。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Synchronized Surface Modification of TiO2 Composite Nanofiber Through Core-Shell Electrospinning
An online surface modification process based on core-shell electrospinning was provided to fabricate functional composite nanofibers. The polyethylene oxide (PEO) solution and titanium dioxide (TiO2) suspension were provided through core and shell channel of spinneret respectively to obtain PEO/TiO2 composite nanofibers. The PEO solution was stretched and solidified into nanofibers, and the TiO2 nanoparticles were embedded into the PEO nanofibers. This method provided a good way to increase the distribution ratio of functional nanoparticles on the nanofiber surface. X-ray diffraction and Fourier transform infrared spectroscopy were used to confirm the materials component of composite nanofibers. The titanium mass content increased to 3.81 wt% by the core-shell electrospinning. The PEO/TiO2 nanofibers enhanced the ultraviolet resistance furcation. This work demonstrates the possibility and validity of using coaxial electrospinning to modify the fiber surface at the same time of electrospinning process, it gives further insight into preparing composite nanofiber materials.
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