一种新型耐盐减阻剂的合成及性能研究

X. Ying, Z. Lang, Chen Pengfei
{"title":"一种新型耐盐减阻剂的合成及性能研究","authors":"X. Ying, Z. Lang, Chen Pengfei","doi":"10.2118/215849-pa","DOIUrl":null,"url":null,"abstract":"\n To solve the problem of poor salt resistance of conventional drag reducers, a hydrophobic associative polymer drag reducer was prepared by inverse emulsion polymerization with acrylamide (AM), methacrylic acid (MAA), 2-acrylamide-2-methylpropane sulfonic acid (AMPS), and hexadecyl dimethyl allyl ammonium chloride (C16DMAAC) as the main monomers. The synthetic product was confirmed as the target product by infrared (IR), nuclear magnetic resonance (NMR), and mass spectrometry (MS). The viscosity-average molecular weight of the prepared drag reducer is 1100×104 g/mol. The pipeline friction results show that the drag reducer has good friction reduction and salt resistance. When the concentration in clean water is 0.06%, the maximum friction reduction rate is 71.1%. When the salinity is 5×104 mg/L, the calcium ion concentration is 2000 mg/L, and the suspended solid content is 500 mg/L, the maximum friction reduction rate is 68.9% when the concentration of the drag reducer is 0.06%. Salt water will not significantly lower the friction reduction rate. If the concentration of the drag reducer is increased to 0.08%, the maximum drag reduction rate will reach 73.8%. The microrheological test results of the friction reducer solution show that, at 0.2% concentration, there is no network structure between friction reducer molecules, which is consistent with Newtonian fluids possessing a certain viscosity. The elasticity index (EI) of the drag reducer solution is basically unchanged over time, maintaining good friction reduction and sand-carrying performance during the shearing process of large displacement pumping.","PeriodicalId":153181,"journal":{"name":"SPE Production & Operations","volume":"55 1","pages":"0"},"PeriodicalIF":0.0000,"publicationDate":"2023-07-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Study on the Synthesis and Properties of a New Salt-Resistant Drag Reducer\",\"authors\":\"X. Ying, Z. Lang, Chen Pengfei\",\"doi\":\"10.2118/215849-pa\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"\\n To solve the problem of poor salt resistance of conventional drag reducers, a hydrophobic associative polymer drag reducer was prepared by inverse emulsion polymerization with acrylamide (AM), methacrylic acid (MAA), 2-acrylamide-2-methylpropane sulfonic acid (AMPS), and hexadecyl dimethyl allyl ammonium chloride (C16DMAAC) as the main monomers. The synthetic product was confirmed as the target product by infrared (IR), nuclear magnetic resonance (NMR), and mass spectrometry (MS). The viscosity-average molecular weight of the prepared drag reducer is 1100×104 g/mol. The pipeline friction results show that the drag reducer has good friction reduction and salt resistance. When the concentration in clean water is 0.06%, the maximum friction reduction rate is 71.1%. When the salinity is 5×104 mg/L, the calcium ion concentration is 2000 mg/L, and the suspended solid content is 500 mg/L, the maximum friction reduction rate is 68.9% when the concentration of the drag reducer is 0.06%. Salt water will not significantly lower the friction reduction rate. If the concentration of the drag reducer is increased to 0.08%, the maximum drag reduction rate will reach 73.8%. The microrheological test results of the friction reducer solution show that, at 0.2% concentration, there is no network structure between friction reducer molecules, which is consistent with Newtonian fluids possessing a certain viscosity. The elasticity index (EI) of the drag reducer solution is basically unchanged over time, maintaining good friction reduction and sand-carrying performance during the shearing process of large displacement pumping.\",\"PeriodicalId\":153181,\"journal\":{\"name\":\"SPE Production & Operations\",\"volume\":\"55 1\",\"pages\":\"0\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2023-07-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"SPE Production & Operations\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.2118/215849-pa\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"SPE Production & Operations","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.2118/215849-pa","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 0

摘要

为解决常规减阻剂耐盐性差的问题,以丙烯酰胺(AM)、甲基丙烯酸(MAA)、2-丙烯酰胺-2-甲基丙烷磺酸(AMPS)和十六烷基二甲基丙烯酰氯化铵(C16DMAAC)为主要单体,通过反相乳液聚合法制备了疏水缔合聚合物减阻剂。合成产物经红外(IR)、核磁共振(NMR)和质谱(MS)证实为目标产物。所制备的减阻剂的粘度-平均分子量为1100×104 g/mol。管道摩擦试验结果表明,该减阻剂具有良好的减摩性能和耐盐性能。在清水中浓度为0.06%时,最大摩擦减少率为71.1%。当矿化度为5×104 mg/L,钙离子浓度为2000 mg/L,悬浮物含量为500 mg/L时,减阻剂浓度为0.06%时,最大减阻率为68.9%。盐水不会显著降低摩擦减少率。当减阻剂浓度增加到0.08%时,最大减阻率可达73.8%。摩擦减速器溶液的微流变学测试结果表明,在0.2%浓度下,摩擦减速器分子之间不存在网状结构,这与具有一定粘度的牛顿流体相一致。减阻液的弹性指数(EI)随时间基本不变,在大排量泵送剪切过程中保持良好的减摩和携砂性能。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Study on the Synthesis and Properties of a New Salt-Resistant Drag Reducer
To solve the problem of poor salt resistance of conventional drag reducers, a hydrophobic associative polymer drag reducer was prepared by inverse emulsion polymerization with acrylamide (AM), methacrylic acid (MAA), 2-acrylamide-2-methylpropane sulfonic acid (AMPS), and hexadecyl dimethyl allyl ammonium chloride (C16DMAAC) as the main monomers. The synthetic product was confirmed as the target product by infrared (IR), nuclear magnetic resonance (NMR), and mass spectrometry (MS). The viscosity-average molecular weight of the prepared drag reducer is 1100×104 g/mol. The pipeline friction results show that the drag reducer has good friction reduction and salt resistance. When the concentration in clean water is 0.06%, the maximum friction reduction rate is 71.1%. When the salinity is 5×104 mg/L, the calcium ion concentration is 2000 mg/L, and the suspended solid content is 500 mg/L, the maximum friction reduction rate is 68.9% when the concentration of the drag reducer is 0.06%. Salt water will not significantly lower the friction reduction rate. If the concentration of the drag reducer is increased to 0.08%, the maximum drag reduction rate will reach 73.8%. The microrheological test results of the friction reducer solution show that, at 0.2% concentration, there is no network structure between friction reducer molecules, which is consistent with Newtonian fluids possessing a certain viscosity. The elasticity index (EI) of the drag reducer solution is basically unchanged over time, maintaining good friction reduction and sand-carrying performance during the shearing process of large displacement pumping.
求助全文
通过发布文献求助,成功后即可免费获取论文全文。 去求助
来源期刊
自引率
0.00%
发文量
0
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
确定
请完成安全验证×
copy
已复制链接
快去分享给好友吧!
我知道了
右上角分享
点击右上角分享
0
联系我们:info@booksci.cn Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。 Copyright © 2023 布克学术 All rights reserved.
京ICP备2023020795号-1
ghs 京公网安备 11010802042870号
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术官方微信