变压器油中溶解气体的红外吸收特性分析

Y. Yun, X. Zhao, X. Li
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引用次数: 4

摘要

故障气体的红外吸收特性是红外光学方法对变压器油中溶解气体进行定性和定量分析的理论基础。本文提出了一种计算给定压力或温度下气体红外吸收光谱的方法。利用HITRAN2004数据库中的光谱参数,研究了CH4、C2H6、C2H4、C2H2、CO、CO2和H2O的红外吸收特性。给出了这些气体在500 ~ 4000cm−1光谱区的红外光谱。分析了吸收谱线的峰吸收系数和半最大值全宽随压力和温度的变化规律。计算和分析结果对于利用傅里叶变换红外光谱法和光声光谱法等红外光学方法在线和离线检测变压器油中溶解气体特别有用。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Infrared absorption properties analysis of dissolved gases in transformer oil
Infrared absorption properties of fault gases are the theoretical bases of qualitative and quantitative analysis of dissolved gases in transformer oil by infrared optical methods. This paper proposed a method that can calculate gaseous infrared absorption spectrum at a given pressure or temperature. Using spectroscopic parameters found in the HITRAN2004 database, the infrared absorption properties of CH4, C2H6, C2H4, C2H2, CO, CO2 and H2O were researched by the method. The infrared spectra of these gases in the spectral region of 500∼4000cm−1 were given. And the laws that the peak absorption coefficient and full width at half maximum value (FWHM) of an absorption line vary with pressure and temperature were also analyzed. Calculation and analysis results are particularly useful for the online and offline detection of dissolved gases in transformer oil by infrared optical methods such as Fourier transform infrared spectrometry and photoacoustic spectrometry.
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