{"title":"303.15K时环己酮(C6H10O)与氯烷的过量摩尔体积","authors":"A. Tripathi, Souvik Sur","doi":"10.48165/bpas.2023.42c.1.2","DOIUrl":null,"url":null,"abstract":"Measurements on excess molar volume by using dilatometer have been made for mixtures of Cyclohexanone with 1-chlorobutane, acetylene tetrachloride, Chloroform and 1,3 dichloropropane at 303.15K and under atmospheric pressure in the liquid state. The obtained data have been fitted with the help of polynomial Redlich-Kister equation and discussed with the point view of molecular interactions in the liquid state. The values of VE have been found to be negative in sign for the mixtures of Cyclohexanone with 1-chlorobutane, acetylene tetrachloride, and chloroform whereas it is positive in sign with 1,3-dichloropropane. The results obtained may be attributed to donor-acceptor interaction for all components in the liquid state.","PeriodicalId":129742,"journal":{"name":"Bulletin of Pure and Applied Sciences-Chemistry","volume":"2 1","pages":"0"},"PeriodicalIF":0.0000,"publicationDate":"2023-06-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Excess Molar Volume for Cyclohexanone (C6H10O) with Chloroalkanes at 303.15K\",\"authors\":\"A. Tripathi, Souvik Sur\",\"doi\":\"10.48165/bpas.2023.42c.1.2\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Measurements on excess molar volume by using dilatometer have been made for mixtures of Cyclohexanone with 1-chlorobutane, acetylene tetrachloride, Chloroform and 1,3 dichloropropane at 303.15K and under atmospheric pressure in the liquid state. The obtained data have been fitted with the help of polynomial Redlich-Kister equation and discussed with the point view of molecular interactions in the liquid state. The values of VE have been found to be negative in sign for the mixtures of Cyclohexanone with 1-chlorobutane, acetylene tetrachloride, and chloroform whereas it is positive in sign with 1,3-dichloropropane. The results obtained may be attributed to donor-acceptor interaction for all components in the liquid state.\",\"PeriodicalId\":129742,\"journal\":{\"name\":\"Bulletin of Pure and Applied Sciences-Chemistry\",\"volume\":\"2 1\",\"pages\":\"0\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2023-06-20\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Bulletin of Pure and Applied Sciences-Chemistry\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.48165/bpas.2023.42c.1.2\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Bulletin of Pure and Applied Sciences-Chemistry","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.48165/bpas.2023.42c.1.2","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Excess Molar Volume for Cyclohexanone (C6H10O) with Chloroalkanes at 303.15K
Measurements on excess molar volume by using dilatometer have been made for mixtures of Cyclohexanone with 1-chlorobutane, acetylene tetrachloride, Chloroform and 1,3 dichloropropane at 303.15K and under atmospheric pressure in the liquid state. The obtained data have been fitted with the help of polynomial Redlich-Kister equation and discussed with the point view of molecular interactions in the liquid state. The values of VE have been found to be negative in sign for the mixtures of Cyclohexanone with 1-chlorobutane, acetylene tetrachloride, and chloroform whereas it is positive in sign with 1,3-dichloropropane. The results obtained may be attributed to donor-acceptor interaction for all components in the liquid state.
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