溶胶-凝胶浸涂法制备纳米锐钛矿型二氧化钛薄膜

Davoud Dastan
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引用次数: 81

摘要

在玻璃衬底上沉积了锐钛型二氧化钛薄膜。在剧烈搅拌下,将底物均匀地浸入溶液中。薄膜在室温下干燥。合成部分以油胺(OM)为表面活性剂,与异丙醇钛(TIP)在室温下进行剧烈搅拌。薄膜样品在550 \(^\circ\)℃下退火15小时。利用x射线衍射(XRD)和拉曼光谱对样品的结构特性进行了研究。用紫外可见光谱法研究了样品的光学性质。XRD结果表明,沉积和退火后的tio\(_2\)薄膜样品具有非晶结构和纯锐钛矿相,拉曼光谱进一步证实了这一结果。紫外可见证实了制备和烧结的TiO \(_2\)薄膜的能带为3.26 eV和3.22 eV,这仅仅是指锐钛型二氧化钛晶体结构的变化。两种样品均具有较高的透光率;78-86%.
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Nanostructured Anatase Titania Thin Films Prepared by Sol-Gel Dip Coating Technique
Anatase titania thin films were deposited on glass substrates. The substrates were dipped matched dipped into the solution under vigorous stirring. The films were dried at room temperature. Oley amine (OM) was used as a surfactant in the synthesis part and it was vigorously stirred with titanium isopropoxide (TIP) at room temperature. The film samples were annealed at 550\(^\circ\)C for 15 hours. X-ray diffraction (XRD) and Raman spectroscopy were used to study the structural properties of samples. The optical properties of samples were investigated by means of ultraviolet visible (UV vis) spectroscopy. XRD results illustrated the amorphous structure and pure anatase phase of TiO\(_2\) for as deposited and annealed thin films samples and these results were further confirmed by Raman spectroscopy. UV-visible corroborates the energy band 3.26 eV and 3.22 eV for as prepared and sintered TiO\(_2\) thin films which simply refers to the change in crystal structure of anatase titania. Furthermore, both samples had high transmittance; almost 78-86%.
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