{"title":"酸性电解质中碳的电极电位","authors":"N. M. Winslow","doi":"10.1149/1.3071830","DOIUrl":null,"url":null,"abstract":"When carbon is exposed to oxygen in the presence of acid, it develops oxidizing characteristics measurable as potential or as capacity to oxidize reducing agents such as ferrous iron. Sorption of both acid and oxygen is essential to the development of oxidizing properties. Quantitative correlations of active oxygen and potential with acid sorption are given for several carbons, and the results of miscellaneous experiments indicating a possible chemical mechanism for the formation of active surface complexes on carbon are presented.","PeriodicalId":118206,"journal":{"name":"Transactions of the Electrochemical Society","volume":"1 1","pages":"0"},"PeriodicalIF":0.0000,"publicationDate":"1947-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"8","resultStr":"{\"title\":\"Electrode Potentials of Carbon in Acid Electrolytes\",\"authors\":\"N. M. Winslow\",\"doi\":\"10.1149/1.3071830\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"When carbon is exposed to oxygen in the presence of acid, it develops oxidizing characteristics measurable as potential or as capacity to oxidize reducing agents such as ferrous iron. Sorption of both acid and oxygen is essential to the development of oxidizing properties. Quantitative correlations of active oxygen and potential with acid sorption are given for several carbons, and the results of miscellaneous experiments indicating a possible chemical mechanism for the formation of active surface complexes on carbon are presented.\",\"PeriodicalId\":118206,\"journal\":{\"name\":\"Transactions of the Electrochemical Society\",\"volume\":\"1 1\",\"pages\":\"0\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"1947-10-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"8\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Transactions of the Electrochemical Society\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1149/1.3071830\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Transactions of the Electrochemical Society","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1149/1.3071830","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Electrode Potentials of Carbon in Acid Electrolytes
When carbon is exposed to oxygen in the presence of acid, it develops oxidizing characteristics measurable as potential or as capacity to oxidize reducing agents such as ferrous iron. Sorption of both acid and oxygen is essential to the development of oxidizing properties. Quantitative correlations of active oxygen and potential with acid sorption are given for several carbons, and the results of miscellaneous experiments indicating a possible chemical mechanism for the formation of active surface complexes on carbon are presented.