三十年微波快速追踪化学反应:阿司匹林案例

2017 SBMO/IEEE MTT-S International Microwave and Optoelectronics Conference (IMOC) Pub Date : 2017-08-01 DOI:10.1109/IMOC.2017.8121154

L. A. Jermolovicius, E. Pouzada, A. Stefanelli, R. B. do Nascimento, E. R. de Castro, J. T. Senise

{"title":"三十年微波快速追踪化学反应:阿司匹林案例","authors":"L. A. Jermolovicius, E. Pouzada, A. Stefanelli, R. B. do Nascimento, E. R. de Castro, J. T. Senise","doi":"10.1109/IMOC.2017.8121154","DOIUrl":null,"url":null,"abstract":"This paper compares empirical chemical kinetic equations for salicylic acid acylation obtained under 2.45 GHz electromagnetic radiation with conventional electric heating. Results show changes in the activation energy value and in reactions orders, which indicate an alteration of the reaction mechanism. This mechanism alteration is accepted as the cause for microwave enhancement of this reaction. A new concept of microwave irradiated chemical reactor used in these experiments is described.","PeriodicalId":171284,"journal":{"name":"2017 SBMO/IEEE MTT-S International Microwave and Optoelectronics Conference (IMOC)","volume":"7 1","pages":"0"},"PeriodicalIF":0.0000,"publicationDate":"2017-08-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Thirty years of fast-tracking chemical reactions with microwaves: Aspirin case\",\"authors\":\"L. A. Jermolovicius, E. Pouzada, A. Stefanelli, R. B. do Nascimento, E. R. de Castro, J. T. Senise\",\"doi\":\"10.1109/IMOC.2017.8121154\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"This paper compares empirical chemical kinetic equations for salicylic acid acylation obtained under 2.45 GHz electromagnetic radiation with conventional electric heating. Results show changes in the activation energy value and in reactions orders, which indicate an alteration of the reaction mechanism. This mechanism alteration is accepted as the cause for microwave enhancement of this reaction. A new concept of microwave irradiated chemical reactor used in these experiments is described.\",\"PeriodicalId\":171284,\"journal\":{\"name\":\"2017 SBMO/IEEE MTT-S International Microwave and Optoelectronics Conference (IMOC)\",\"volume\":\"7 1\",\"pages\":\"0\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2017-08-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"2017 SBMO/IEEE MTT-S International Microwave and Optoelectronics Conference (IMOC)\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1109/IMOC.2017.8121154\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"2017 SBMO/IEEE MTT-S International Microwave and Optoelectronics Conference (IMOC)","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1109/IMOC.2017.8121154","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}

引用次数: 0

摘要

比较了2.45 GHz电磁辐射与常规电加热条件下水杨酸酰化反应的经验化学动力学方程。结果表明，反应顺序和活化能发生了变化，表明反应机理发生了改变。这种机理的改变被认为是微波增强该反应的原因。介绍了微波辐照化学反应器的新概念。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

查看原文本刊更多论文

Thirty years of fast-tracking chemical reactions with microwaves: Aspirin case

This paper compares empirical chemical kinetic equations for salicylic acid acylation obtained under 2.45 GHz electromagnetic radiation with conventional electric heating. Results show changes in the activation energy value and in reactions orders, which indicate an alteration of the reaction mechanism. This mechanism alteration is accepted as the cause for microwave enhancement of this reaction. A new concept of microwave irradiated chemical reactor used in these experiments is described.

求助全文

通过发布文献求助，成功后即可免费获取论文全文。去求助

来源期刊

2017 SBMO/IEEE MTT-S International Microwave and Optoelectronics Conference (IMOC)

自引率

0.00%

发文量