用数学模型研究现代炼油厂催化剂寿命周期的风险

R. A. Ashrafov, A. M. Nuriev
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引用次数: 0

摘要

本文讨论了含铂催化剂尺寸对焦炭碎片特性影响的研究结果,以及在催化重整装置和催化裂化装置氧化再生过程中焦炭燃烧的数学建模方法,以减少现代炼油厂使用的昂贵催化剂过早损失生命周期的风险。在研究含铂催化剂焦炭燃烧过程中揭示的动力学模式使我们提出了一种新的反应机理。编制了描述个别反应的化学计量比。基于所提出的机理,采用了路线的动力学方程。基于获得的动力学方程组,并假定没有径向温度梯度的情况下,与排热过程的浓度和速度,提出了热量平衡方程。将模型参数作为炼油企业工艺过程风险分析的因素。开发的过程数学模型的多功能性使其能够应用于解决改造和开裂装置的管理问题,以减少风险因素
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Risk Research by Mathematical Modeling to Increase the Life Cycle of Catalysts Used in Modern Refineries
This article discusses the results of a study of the effect of the size of a platinum-containing catalyst onthe characteristics of coke fragments and the method of mathematical modeling of coke burning in the process of oxidative regeneration both at catalytic reforming plants and at catalytic cracking plants, in order to reduce the risks of premature loss of the life cycle of expensive catalysts used at modern refineries.The revealed kinetic patterns obtained during the study of coke burning of a platinum-containing catalyst allowed us to propose a new reaction mechanism. Stoichiometric ratios describing individual reactions are compiled. Based on the proposed mechanism,kinetic equations for routes are adopted. Based on the obtained system of kinetic equations and assuming the absence of radial temperature gradients, concentration and rate of the process with heat removal, the heat balance equation is proposed. The parameters of the model are considered as factors of risk analysis of technological processes atthe refinery enterprises. The versatility of the developed mathematical model of the process makes it possible to apply it to solving problems of managing both reforming and cracking installations, in order to reduce risk factors
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