超纯粘弹性阻尼聚合物及相关低放气材料

Jeff W. McCutcheon
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摘要

多功能材料在振动、冲击和声学控制方面的成功应用的关键往往是材料的正确选择、几何设计和最佳应用。在多功能材料的几何设计和优化应用方面已经做了大量的工作。下一步是改进被动阻尼材料本身。过去对被动材料的改进通常集中在阻尼性能(损耗系数、存储模量)、材料性能(丙烯酸、硅树脂等)和增强特性(导热、导电等)方面。超纯粘弹性阻尼聚合物是对被动阻尼聚合物的最新需求之一。这种新一代材料的用途越来越广泛,因为使用被动材料的敏感环境需要一种不会对该环境中的组件产生负面影响的材料。这种新一代的被动材料需要在有机材料放气、阴离子、催化剂和硅氧烷方面达到超纯。除了高纯度的粘弹性阻尼聚合物要求外,在相同环境中使用的相关聚合物材料(环氧树脂,层压粘合剂和胶带)也必须具有类似的低放气,超纯,超洁净,电子级或洁净室性能指定。如果不这样做,环境可能会受到污染,并抵消使用清洁阻尼材料的部分好处。这也需要了解用于确定每种产品清洁度性能的测试方法,因为所有的测试方法是不相等的,可能会给出明显不同的测试结果。一个例子是比较有机放气测试的聚合物样品,使用静态顶空气相色谱/质谱(GC/MS)和动态顶空气相色谱/质谱。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Ultra-Pure Viscoelastic Damping Polymers and Associated Low Outgassing Materials
The key to successful multifunctional materials applications for vibration, shock and acoustic control is often the proper selection of materials, geometric design and optimum application. Much work has been done in the areas of geometric designs and optimum application of the multi-functional materials. The next step is improvements in the passive damping materials themselves. The improvement in the passive materials in the past has often focused on the areas of improved damping performance (loss factor, storage modulus), material performance (acrylics, silicones, etc.) and enhanced features (thermally conductive, electrically conductive, etc). One of the newest requirements for passive damping polymers is in the area of ultra-pure viscoelastic damping polymers. This new generation of materials is finding growing use because the sensitive environment where the passive material is used require a material that will not negatively impact the components in that environment. This new generation of passive materials needs to be ultra-pure with respect to organic material outgassing, anions, catalysts and siloxanes. In addition to the viscoelastic damping polymer requirements for high purity, the associated polymeric materials (epoxies, laminating adhesives and tapes) used in the same environment must also be of a similar low outgassing, ultra-pure, ultra-clean, electronics grade or clean room performance designation. If this is not done, the environment could become contaminated and negate a portion of the benefit of using the clean damping material. This also requires an understanding of the test method used to determine each product’s cleanliness performance, as all test methods are not equal and can give significantly different test results. An example is comparing a polymer sample tested for organic outgassing and using a static headspace gas chromatography/mass spectroscopy (GC/MS) and a dynamic headspace GC/MS.
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