一种新型冠醚硫代氨基脲的合成及其反应性

Proceedings of The 22nd International Electronic Conference on Synthetic Organic Chemistry Pub Date : 2018-11-14 DOI:10.3390/ECSOC-22-05686

Fatima Lucio Martinez, J. M. Vila, Francisco Reigosa, P. Munín, J. M. Ortigueira, M. T. Pereira

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引用次数: 0

摘要

在过去的几年里，含有冠醚部分的钯环化合物几乎没有被研究过，尽管它们提供了将冠醚应用于钯环的催化行为的传感器的可能性。这可能是因为它们与二氧化硅存在强烈的相互作用，使得新产品的纯化成为一项艰巨的任务。然而，在这篇通讯中，我们提出了一个新的含15冠5醚的palladacycle的合成和表征。

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Synthesis and reactivity of a new type of crown ether thiosemicarbazone

: Palladacycle compounds containing a crown-ether moiety in their structure have been scarcely studied in the past years, although they offer the possibility of combining the crown-ether application as sensors with the catalytic behavior of palladacycles. Maybe the reason for this is because they present a strong interaction with silica making the purification of the new products a difficult task. Nevertheless, in this communication we present the synthesis and characterization of a new palladacycle bearing a 15-crown-5-ether.

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Proceedings of The 22nd International Electronic Conference on Synthetic Organic Chemistry

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