{"title":"氰化物桥接Nd(III)-Fe(III)配合物的H/D同位素效应和磁性能","authors":"T. Akitsu, Yusuke Kimoto, Y. Yamada, K. Nomura","doi":"10.1524/RCPR.2011.0077","DOIUrl":null,"url":null,"abstract":"Abstract We have prepared four H/D isotope forms of Nd(DMF)4(H2O)3Fe(CN)6·H2O (DMF = N,N-dimethylformamide) by using D2O or DMF-d1. Temperature dependence of magnetization exhibits H/D isotope effects resulting from intermolecular hydrogen bonds. Temperature dependence of Fe 2p3/2 and 2p1/2 XAS and 57Fe Mössbauer spectra suggested that the influence of coordination environment could be distiguished from the influence of crystal lattice based on preliminary crystallographic results.","PeriodicalId":338467,"journal":{"name":"Proceedings in Radiochemistry","volume":"76 1","pages":"0"},"PeriodicalIF":0.0000,"publicationDate":"2011-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"1","resultStr":"{\"title\":\"H/D isotope effect and magnetic properties of cyanide-bridged Nd(III)-Fe(III) complex\",\"authors\":\"T. Akitsu, Yusuke Kimoto, Y. Yamada, K. Nomura\",\"doi\":\"10.1524/RCPR.2011.0077\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Abstract We have prepared four H/D isotope forms of Nd(DMF)4(H2O)3Fe(CN)6·H2O (DMF = N,N-dimethylformamide) by using D2O or DMF-d1. Temperature dependence of magnetization exhibits H/D isotope effects resulting from intermolecular hydrogen bonds. Temperature dependence of Fe 2p3/2 and 2p1/2 XAS and 57Fe Mössbauer spectra suggested that the influence of coordination environment could be distiguished from the influence of crystal lattice based on preliminary crystallographic results.\",\"PeriodicalId\":338467,\"journal\":{\"name\":\"Proceedings in Radiochemistry\",\"volume\":\"76 1\",\"pages\":\"0\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2011-09-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"1\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Proceedings in Radiochemistry\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1524/RCPR.2011.0077\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Proceedings in Radiochemistry","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1524/RCPR.2011.0077","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
H/D isotope effect and magnetic properties of cyanide-bridged Nd(III)-Fe(III) complex
Abstract We have prepared four H/D isotope forms of Nd(DMF)4(H2O)3Fe(CN)6·H2O (DMF = N,N-dimethylformamide) by using D2O or DMF-d1. Temperature dependence of magnetization exhibits H/D isotope effects resulting from intermolecular hydrogen bonds. Temperature dependence of Fe 2p3/2 and 2p1/2 XAS and 57Fe Mössbauer spectra suggested that the influence of coordination environment could be distiguished from the influence of crystal lattice based on preliminary crystallographic results.
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