石墨烯/碳纳米管纤维增强聚合物基纳米复合材料的电、介电、机械和电磁屏蔽研究

Z. Zubair, M. Rizwan, Fatima Shehzadi, K. Shaker, Fiaz Hussain, H. F. Shakir
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引用次数: 0

摘要

目的:采用热还原氧化石墨烯(TRGO)和多壁碳纳米管(CNTs)作为导电纳米填料制备环氧玻璃纤维增强复合材料。对其电气、机械、介电和电磁干扰屏蔽性能进行了分析和比较。方法:采用改进hummers法制备TRGO, x射线衍射光谱显示其厚度为6 ~ 8nm的碳六方结构。这些复合材料的拉伸、弯曲和冲击强度相当,并且随着填料含量的增加而增加。比较了TRGO和CNTs对复合材料交直流电导率的影响,结果表明,增加TRGO含量对复合材料电导率的提高效果略好于填充CNTs的复合材料。结果:在更高频率(5MHz)下,添加TRGO的复合材料的介电性能也比添加CNTs的复合材料得到了更好的改善。当添加2.0% TRGO和CNTs时,在较低频率下观察到的最大SET为32dB, TRGO基复合材料即使在较高频率下也能保持其性能,而在5MHz频率下,CNTs基复合材料的SET值降至24dB。结论:聚合物复合材料的分散状态、填料的组成及其与基体的相互作用是影响电磁干扰屏蔽性能的重要因素。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Electric, Dielectric, Mechanical and Emi Shielding Study of Fiber Reinforced Polymer Based Nanocomposites with the Incorporation of Graphene/Cnts
Objective: Glass fiber reinforced composites with epoxy were prepared using thermally reduced graphene oxide (TRGO) and multiwall carbon nanotubes (CNTs) as electrically conductive nano filler. Electrical, mechanical, dielectric and electromagnetic interference (EMI) shielding properties were analyzed and compared. Methods: TRGO was prepared by modified hummers method and X-ray diffraction spectra showed the carbon hexagonal structure with 6-8nm of thickness. Tensile, flexural and impact strength of these composites was comparable and increase with increasing filler content. The effect of TRGO and CNTs on AC & DC conductivity of composites was also compared, which showed that increasing the TRGO content increased the electrical conductivity little better than that of CNTs filled composite. Results: The dielectric properties also improved better for composite incorporating TRGO than with the CNTs, at higher frequency (5MHz). With addition of 2.0% TRGO and CNTs, the maximum SET observed was 32dB at lower frequency, with TRGO-based composite manage to maintain its performance even at higher frequency whereas, this value dropped to 24dB for CNT-based composite at 5MHz of frequency. Conclusion: The dispersion state, the composition of the fillers, and their interaction with matrix are the most important factors in these polymeric composites for the development in EMI shielding effectiveness.
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