压制成型制备双极板用环氧/石墨/碳纳米管体系的固化条件

B. C. Choi, J. Lee, J. Lee, H. Lee
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引用次数: 1

摘要

以环氧/石墨复合材料和不同碳纳米管(CNT)为原料,采用压制成型工艺制备了聚合物电解质膜燃料电池(PEMFC)的双极板。为了确定温度和时间的固化条件,采用差示扫描量热法(DSC)分析,并将数据引入Kissinger表达式和等转换表达式,得到活化能和指前因子等动力学参数。Kissinger表达的活化能为82.22 kJ/mol,等转化表达的活化能为84 ~ 88 kJ/mol。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Cure condition of epoxy/graphite/CNT system for the preparation of bipolar plate by press molding
A bipolar plate for polymer electrolyte membrane fuel cells (PEMFC) was prepared from epoxy/graphite compounds with various carbon nanotube (CNT) using press molding process. In order to decide the cure condition of temperature and time, differential scanning calorimetry (DSC) analysis was carried out and the data was introduced to Kissinger expression and isoconversional expression to get kinetic parameters such as activation energy and pre-exponential factor. Activation energy from Kissinger expression was 82.22 kJ/mol and that from isoconversional expression was 84∼88 kJ/mol.
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