{"title":"配位剂的合成与研究,用于合成新的配位化合物","authors":"Ghenadie Chiriac, Sergiu Codreanu","doi":"10.36120/2587-3644.v13i1.100-109","DOIUrl":null,"url":null,"abstract":"Two compounds were obtained from the condensation reaction of semicarbazide (hydrazinecarboxamide) and semithiocarbohydrazide (hydrazinecarbothioamide) compounds with a 3-pyridinecarboxaldehyde carbonyl compound: (E)-1-(pyridin-3-ylmethylene)thiourea (L-1) and (E)-1-(pyridin-3-ylmethylene)urea (L-1) (L-2). The structure and composition of these compounds were determined using theoretical calculations with the GAMESS software package and IR spectroscopy. The new organic molecules L-1 and L-2 have the potential to be used as mono- or bidentate coordinating agents in the construction of coordination compounds with various useful properties.","PeriodicalId":340784,"journal":{"name":"Acta et commentationes: Ştiinţe Exacte şi ale Naturii","volume":"428 1","pages":"0"},"PeriodicalIF":0.0000,"publicationDate":"2022-11-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Synthesis and study of coordinating agents for the synthesis of new coordination compounds\",\"authors\":\"Ghenadie Chiriac, Sergiu Codreanu\",\"doi\":\"10.36120/2587-3644.v13i1.100-109\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Two compounds were obtained from the condensation reaction of semicarbazide (hydrazinecarboxamide) and semithiocarbohydrazide (hydrazinecarbothioamide) compounds with a 3-pyridinecarboxaldehyde carbonyl compound: (E)-1-(pyridin-3-ylmethylene)thiourea (L-1) and (E)-1-(pyridin-3-ylmethylene)urea (L-1) (L-2). The structure and composition of these compounds were determined using theoretical calculations with the GAMESS software package and IR spectroscopy. The new organic molecules L-1 and L-2 have the potential to be used as mono- or bidentate coordinating agents in the construction of coordination compounds with various useful properties.\",\"PeriodicalId\":340784,\"journal\":{\"name\":\"Acta et commentationes: Ştiinţe Exacte şi ale Naturii\",\"volume\":\"428 1\",\"pages\":\"0\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2022-11-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Acta et commentationes: Ştiinţe Exacte şi ale Naturii\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.36120/2587-3644.v13i1.100-109\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Acta et commentationes: Ştiinţe Exacte şi ale Naturii","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.36120/2587-3644.v13i1.100-109","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Synthesis and study of coordinating agents for the synthesis of new coordination compounds
Two compounds were obtained from the condensation reaction of semicarbazide (hydrazinecarboxamide) and semithiocarbohydrazide (hydrazinecarbothioamide) compounds with a 3-pyridinecarboxaldehyde carbonyl compound: (E)-1-(pyridin-3-ylmethylene)thiourea (L-1) and (E)-1-(pyridin-3-ylmethylene)urea (L-1) (L-2). The structure and composition of these compounds were determined using theoretical calculations with the GAMESS software package and IR spectroscopy. The new organic molecules L-1 and L-2 have the potential to be used as mono- or bidentate coordinating agents in the construction of coordination compounds with various useful properties.