配位剂的合成与研究,用于合成新的配位化合物

Ghenadie Chiriac, Sergiu Codreanu
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引用次数: 0

摘要

由氨基脲(肼甲酰胺)和半硫代氨基脲(肼甲乙酰胺)与3-吡啶甲醛羰基化合物缩合反应得到两个化合物:(E)-1-(吡啶-3-基亚甲基)硫脲(L-1)和(E)-1-(吡啶-3-基亚甲基)尿素(L-1) (L-2)。这些化合物的结构和组成通过GAMESS软件包和红外光谱进行理论计算。新的有机分子L-1和L-2有潜力作为单齿或双齿配位剂,用于构建具有各种有用性质的配位化合物。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Synthesis and study of coordinating agents for the synthesis of new coordination compounds
Two compounds were obtained from the condensation reaction of semicarbazide (hydrazinecarboxamide) and semithiocarbohydrazide (hydrazinecarbothioamide) compounds with a 3-pyridinecarboxaldehyde carbonyl compound: (E)-1-(pyridin-3-ylmethylene)thiourea (L-1) and (E)-1-(pyridin-3-ylmethylene)urea (L-1) (L-2). The structure and composition of these compounds were determined using theoretical calculations with the GAMESS software package and IR spectroscopy. The new organic molecules L-1 and L-2 have the potential to be used as mono- or bidentate coordinating agents in the construction of coordination compounds with various useful properties.
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