氧化铜锡纳米颗粒对废水中重金属的高效吸附

A. E. Abdelaal, M. Abdel-Motaleb, M. E. Kady, A. Hamed
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引用次数: 1

摘要

从废水中去除重金属对于解决全球水危机至关重要。过渡金属氧化物纳米颗粒是这些应用的有希望的候选者。本文从商业前驱体出发,采用简单经济的感知方法制备了氧化铜和氧化锡纳米颗粒。所得的氧化铜纳米颗粒呈扁平状,氧化锡纳米颗粒呈球形。制备的纳米颗粒均为结晶相,其中氧化铜纳米颗粒为单斜晶相,氧化锡纳米颗粒为四方晶相。氧化铜和氧化锡纳米颗粒的晶粒尺寸分别为12 nm和13 nm。所制备的氧化铜和氧化锡纳米颗粒可去除废水中的镉和铅离子。研究了不同吸附参数下的吸附过程,如;接触时间和pH值。氧化铜纳米粒子对Pb离子的最高去除率约为99%。该吸附过程在中性介质(pH 7)中30 min后进行。而在相同条件下,氧化锡纳米颗粒的去除率约为94%。另一方面,氧化铜纳米粒子对Cd离子的去除率约为57%。在部分酸性介质(pH 6)中,该吸附过程在30 min后进行。而在相同条件下,氧化锡纳米颗粒去除约54%。最后,强烈建议使用氧化铜和氧化锡纳米颗粒作为重金属去除应用的有前途的吸附剂。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Facile Preparation of Copper and Tin Oxide Nanoparticles as Efficient Adsorbent of Heavy Metals from Wastewater
Heavy metal removal from waste water is essential to solve the global water crises. Transition metal oxide nanoparticles are promising candidates for these applications. Herein, Copper oxide and Tin oxide nanoparticles have been prepared via Facile and economic perception method starting from commercial precursors. The obtained nanoparticles were in flack-like shape and spherical shape for Copper oxide and Tin oxide nanoparticles, respectively. All prepared nanoparticles are in crystalline phases, where the prepared Copper oxide and Tin oxide nanoparticles were in monoclinic and tetragonal crystalline phases, respectively. The crystal size of Copper oxide and Tin oxide nanoparticles were 12 nm and 13 nm respectively. Cd and Pb ions were removed from wastewater by the obtained Copper oxide and Tin oxide nanoparticles. The adsorption processes were studied under various parameters, such as; contact time and pH values. The highest removal uptake was about ~99% of Pb ions were recorded for Copper oxide nanoparticles. This uptake process carried out after 30 min in a neutral medium (pH 7). While, Tin oxide nanoparticles removed about ~94% at the same conditions. On the other hand, Copper oxide nanoparticles removed about ~ 57% from Cd ions. This uptake process carried out after 30 min in a partially acidic medium (pH 6). While, Tin oxide nanoparticles removed about ~54% at the same conditions. Finally, it is highly recommended to use Copper oxide and Tin oxide nanoparticles as promising adsorbents for heavy metal removal applications.
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