磁助化学分离法制备铀转化厂核废料的最终处理

A. Ghaemi, Mehdi Maghsudi, Fatemeh Hanifpour, M. Samadfam
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引用次数: 1

摘要

采用溶剂包覆磁性纳米颗粒的方法,从伊斯法罕铀转化溶剂萃取工艺的萃余液中分离出铀。采用化学共沉淀法合成了这些颗粒,并用XRD、TEM和TGA等方法对其进行了分析。用D2EHPA对颗粒表面进行修饰,并用FT-IR法对其进行分析。结果表明,0.5 M硝酸和25% w/w D2EHPA对纳米粒子的提铀率最高。溶剂萃取装置萃余液的铀含量降至允许值后,可安全处理。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Preparation of a Uranium Conversion Plant's Nuclear Waste for Final Disposal by Means of Magnetically Assisted Chemical Separation
Uranium is separated from the raffinate of Isfahan's uranium conversion solvent extraction process by means of solvent coated magnetic nanoparticles. These particles were synthesized via chemical co-precipitation and were analyzed by XRD, TEM and TGA methods. The particles' surface were modified with D2EHPA and analyzed with FT-IR method. The results revealed that 0.5 M nitric acid and 25% w/w D2EHPA on nanoparticles gives the maximum uranium extraction yield. The raffinate of the solvent extraction plant can be disposed safely after its uranium content reduces to the allowable values.
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