Youssra Aghoutane, N. E. Bari, Zoubida Laghrari, B. Bouchikhi
{"title":"P","authors":"Youssra Aghoutane, N. E. Bari, Zoubida Laghrari, B. Bouchikhi","doi":"10.1201/9781420049855-19","DOIUrl":null,"url":null,"abstract":"Fenthion, an organophosphate insecticide, is a cholinesterase inhibitor and is highly toxic. An electrochemical sensor based on molecularly imprinted polymer is developed here for its detection. For this purpose, 2-aminothiophenol mixed with gold nanoparticles was immobilised on screen-printed gold electrodes. The FEN pattern was then fixed before being covered with 2-aminothiophenol. Cyclic voltammetry, differential pulse voltammetry and electrochemical impedance spectroscopy methods were used for the electrochemical characterisation. The low detection limit is 0.04 μg/mL over a range of 0.01–17.3 μg/mL. The sensor was successfully applied for the determination of FEN in olive oil samples with high recovery values.","PeriodicalId":432852,"journal":{"name":"Dictionary of Material Science and High Energy Physics","volume":"45 1","pages":"0"},"PeriodicalIF":0.0000,"publicationDate":"2018-10-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"P\",\"authors\":\"Youssra Aghoutane, N. E. Bari, Zoubida Laghrari, B. Bouchikhi\",\"doi\":\"10.1201/9781420049855-19\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Fenthion, an organophosphate insecticide, is a cholinesterase inhibitor and is highly toxic. An electrochemical sensor based on molecularly imprinted polymer is developed here for its detection. For this purpose, 2-aminothiophenol mixed with gold nanoparticles was immobilised on screen-printed gold electrodes. The FEN pattern was then fixed before being covered with 2-aminothiophenol. Cyclic voltammetry, differential pulse voltammetry and electrochemical impedance spectroscopy methods were used for the electrochemical characterisation. The low detection limit is 0.04 μg/mL over a range of 0.01–17.3 μg/mL. The sensor was successfully applied for the determination of FEN in olive oil samples with high recovery values.\",\"PeriodicalId\":432852,\"journal\":{\"name\":\"Dictionary of Material Science and High Energy Physics\",\"volume\":\"45 1\",\"pages\":\"0\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2018-10-08\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Dictionary of Material Science and High Energy Physics\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1201/9781420049855-19\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Dictionary of Material Science and High Energy Physics","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1201/9781420049855-19","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Fenthion, an organophosphate insecticide, is a cholinesterase inhibitor and is highly toxic. An electrochemical sensor based on molecularly imprinted polymer is developed here for its detection. For this purpose, 2-aminothiophenol mixed with gold nanoparticles was immobilised on screen-printed gold electrodes. The FEN pattern was then fixed before being covered with 2-aminothiophenol. Cyclic voltammetry, differential pulse voltammetry and electrochemical impedance spectroscopy methods were used for the electrochemical characterisation. The low detection limit is 0.04 μg/mL over a range of 0.01–17.3 μg/mL. The sensor was successfully applied for the determination of FEN in olive oil samples with high recovery values.