纳米尺度蛋白石孔隙中Pb3(P0.5 V0.5O4)2结晶的拉曼光谱研究

A. Yevchik, V. Moiseyenko, M. Derhachov, S. Plaksin, R. Levchenko
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引用次数: 1

摘要

介绍了合成蛋白石孔隙中结晶介质Pb3(P0.5V0.5O4)2的拉曼光谱研究结果。将这些光谱与单晶状态下Pb3(P0.5 V0.5O4)2的拉曼光谱进行了比较分析。通过对光谱的拟合,可以揭示光谱线的位置和半宽的变化。结果表明,这些影响可能是由于合成蛋白石纳米孔中的结晶作用导致Pb3(P0.5V0.5O4)2分子内部键长发生变化所致。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Study of Raman Spectra of Pb3(P0.5 V0.5O4)2Crystallized in Nanoscale Opal Pores
The results of Raman spectra investigation of dielectric Pb3(P0.5V0.5O4)2crystallized in pores of synthetic opal are presented. The comparative analysis of these spectra with Raman spectra of Pb3(P0.5 V0.5O4)2in the monocrystalline state is carried out. Due to fitting o the spectra it was possible to reveal the changes in position of the spectral lines and their half-widths. It was shown that these effects may be caused by changing in the lengths of bonds inside the Pb3(P0.5V0.5O4)2molecule as a result of crystallization in nano-sized pores of synthetic opal.
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