DetaClad™高温高压氢气应用特性分析

Olivier Sarrat, C. Prothe, T. Delahanty
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引用次数: 0

摘要

在考虑高温损伤机制时,最具挑战性的决定之一与在高压高温下在含氢环境中工作的厚壁压力容器有关。加氢处理或加氢裂化反应器通常属于这一类,通常有一个奥氏体不锈钢衬里,以保护压力容器的内侧免受腐蚀。碳钢因高温氢侵蚀而产生脆化,要求选用含有Cr、Mo、v等合金元素的钢。相似条件下熔覆界面剥离的高风险也要求选用最合适的熔覆工艺。最重要的是要确保界面能够支持高压氢气和由重载内部产生的应力。在这些极端操作条件下,对DetaClad™界面进行了表征研究。进行了150多次测试,并得出结论,DetaClad™适用于如此苛刻的操作条件下的材料选择。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
DetaClad™ Characterization for High-Temperature and High-Pressure Hydrogen Service
When it comes to considering high-temperature damage mechanisms, one of the most challenging decisions is related to heavy-wall pressure vessels that operate at high pressure and high temperature in a hydrogen containing environment. Hydrotreatment or hydrocracking reactors typically fall under this category and often have an austenitic stainless-steel lining to protect the inner side of the pressure vessel from corrosion. Embrittlement of the carbon steel caused by High-Temperature Hydrogen Attack requires selecting steel with alloying elements such as Cr, Mo and V. The high risks of disbonding of the cladding interface under similar conditions also requires the selection of the most appropriate cladding technology. It is the upmost importance to ensure the interface will support the high-pressure hydrogen and the stresses generated by the heavily loaded internals. A study around characterizing the DetaClad™ interface was conducted under these extreme operating conditions. More than 150 tests were conducted and coming to the conclusion that DetaClad™ is appropriate for material selection under such demanding operating conditions.
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