{"title":"溶液中质子转移反应的动力学氘同位素效应","authors":"J. Sühnel","doi":"10.1080/10256018608623605","DOIUrl":null,"url":null,"abstract":"The theoretical models for the treatment of the kinetic isotope effect of proton-transfer reactions (tunneling, Marcus and quantum-statistical mechanical model) are described. Scope and limits of these models are discussed with respect to intermolecular interaction, free energy relations, temperature, solvent and pressure dependence, and ultrafast protontransfer.","PeriodicalId":370919,"journal":{"name":"März 1986","volume":"10 1","pages":"0"},"PeriodicalIF":0.0000,"publicationDate":"1986-12-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"3","resultStr":"{\"title\":\"The Kinetic Deuterium Isotope Effect of Proton Transfer Reactions in Solution\",\"authors\":\"J. Sühnel\",\"doi\":\"10.1080/10256018608623605\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"The theoretical models for the treatment of the kinetic isotope effect of proton-transfer reactions (tunneling, Marcus and quantum-statistical mechanical model) are described. Scope and limits of these models are discussed with respect to intermolecular interaction, free energy relations, temperature, solvent and pressure dependence, and ultrafast protontransfer.\",\"PeriodicalId\":370919,\"journal\":{\"name\":\"März 1986\",\"volume\":\"10 1\",\"pages\":\"0\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"1986-12-31\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"3\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"März 1986\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1080/10256018608623605\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"März 1986","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1080/10256018608623605","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
The Kinetic Deuterium Isotope Effect of Proton Transfer Reactions in Solution
The theoretical models for the treatment of the kinetic isotope effect of proton-transfer reactions (tunneling, Marcus and quantum-statistical mechanical model) are described. Scope and limits of these models are discussed with respect to intermolecular interaction, free energy relations, temperature, solvent and pressure dependence, and ultrafast protontransfer.
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