碳酸碱和氯化碱盐岩心的力学性能

J. Yaokawa, D. Miura, K. Anzai, Youji Yamada, H. Yoshii
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引用次数: 2

摘要

采用4点弯曲试验、维氏硬度测定、凝固组织和断口SEM观察等方法,研究了由nacl - nazc03、KCI-KzC03、KCI-NaCl和KZC03-NazC03二元盐体系组成的高压压铸用盐芯的强度。采用恒模法制备了10k过热熔盐弯曲试样。弯曲试验结果表明,KCI-KzC03二元体系具有相当高的强度,超过20 MPa左右。而且,NaCI-NazC03体系的强度值比KCI-KzC03体系的强度值更高,获得了特别高的强度。NaCI-NazC03体系的维氏硬度高于KCI-KzC03体系。与这些二元体系相比,KCI-NaCl和KZC03-NazC03二元盐体系的盐芯由于固溶相与熔盐结晶相分离,不能通过混合盐进行强化。在NaCI-NazC03体系的凝固组织中,存在枝晶或椭圆状初生相和细共晶相。由于裂纹扩展受初生相和细共晶相的偏转,盐岩心可以得到强化。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Mechanical Properties of Salt Core Comprised of Alkali Carbonate and Alkali Chloride
The strength of salt core comprised of NaCI-NazC03, KCI-KzC03, KCI-NaCl and KZC03-NazC03 binary salt systems was investigated in order to develop expendable core for high pressure die casting using 4-point bending test, Vickers hardness measurement, and SEM observation of solidification structures and fracture surfaces. Bending specimens were fabricated from 10 K superheated molten salts by the permanent mold method. The results of the bending test showed that the KCI-KzC03 binary system offers quite high strength exceeding about 20 MPa. Moreover, especially high strength was obtained for the NaCI-NazC03 system whose strength value is higher than that of the KCI-KzC03 system. Also, the Vickers hardness of the NaCI-NazC03 system is higher than that of KCI-KzC03 system. In contrast to these binary systems, salt cores made of KCI-NaCl and KZC03-NazC03 binary salt systems could not be strengthened by mixing salt, due to phase separation of the solid solution phase crystallized from molten salt . In the solidification structures of NaCI-NazC03 system, dendritic or elliptic shaped primary phase and fine eutectic phase were found. As crack propagation is deflected by both the primary phase and fine eutectic phase, salt cores can be strengthened.
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