Faez S. Al-Shibli, Raed K. Al-Tamemi, Khansa A. R. Al-Assdi
{"title":"丁香酚制润滑油抗氧化化合物的合成","authors":"Faez S. Al-Shibli, Raed K. Al-Tamemi, Khansa A. R. Al-Assdi","doi":"10.36329/jkcm/2022/v2.i9.13318","DOIUrl":null,"url":null,"abstract":" In this study new antioxidant compounds were prepared by (thiol-ene) click chemistry, where these compounds were prepared using (1:1) mole ratio of (thiol : eugenol) in the presence of benzoyl peroxide as initiator and the reaction is carried out at (100 0C) for (9) hrs. \n (FT-IR), (1HNMR), and mass spectroscopy were used to characterize the synthesized compounds. They were evaluated as antioxidants by adding compounds to base oil and lubricant oil, where they showed high antioxidant activity against lubricant oil oxidation processes.","PeriodicalId":439004,"journal":{"name":"Journal of Kufa for Chemical Sciences","volume":"18 1","pages":"0"},"PeriodicalIF":0.0000,"publicationDate":"2023-08-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Synthesis of the Antioxidant Compounds from the Eugenol to the Lubricating Oils\",\"authors\":\"Faez S. Al-Shibli, Raed K. Al-Tamemi, Khansa A. R. Al-Assdi\",\"doi\":\"10.36329/jkcm/2022/v2.i9.13318\",\"DOIUrl\":null,\"url\":null,\"abstract\":\" In this study new antioxidant compounds were prepared by (thiol-ene) click chemistry, where these compounds were prepared using (1:1) mole ratio of (thiol : eugenol) in the presence of benzoyl peroxide as initiator and the reaction is carried out at (100 0C) for (9) hrs. \\n (FT-IR), (1HNMR), and mass spectroscopy were used to characterize the synthesized compounds. They were evaluated as antioxidants by adding compounds to base oil and lubricant oil, where they showed high antioxidant activity against lubricant oil oxidation processes.\",\"PeriodicalId\":439004,\"journal\":{\"name\":\"Journal of Kufa for Chemical Sciences\",\"volume\":\"18 1\",\"pages\":\"0\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2023-08-28\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Kufa for Chemical Sciences\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.36329/jkcm/2022/v2.i9.13318\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Kufa for Chemical Sciences","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.36329/jkcm/2022/v2.i9.13318","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Synthesis of the Antioxidant Compounds from the Eugenol to the Lubricating Oils
In this study new antioxidant compounds were prepared by (thiol-ene) click chemistry, where these compounds were prepared using (1:1) mole ratio of (thiol : eugenol) in the presence of benzoyl peroxide as initiator and the reaction is carried out at (100 0C) for (9) hrs.
(FT-IR), (1HNMR), and mass spectroscopy were used to characterize the synthesized compounds. They were evaluated as antioxidants by adding compounds to base oil and lubricant oil, where they showed high antioxidant activity against lubricant oil oxidation processes.