常压等离子体射流合成金纳米颗粒

T. Habib, B. Caillier, J. Caiut
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引用次数: 0

摘要

不同形态的等离子体放电由于其不同的应用而引起了人们的广泛关注。特别是,等离子体射流与液体接触是一种简单而廉价的金属纳米颗粒合成技术。其主要优点是等离子体羽流中存在多种物质,可以在溶液中引起快速的化学反应。金纳米颗粒因其独特的物理、光学和化学性质而成为许多研究人员关注的焦点。它们被用于各种领域,它们的特性取决于它们的大小和形态。在这项工作中,研究了在PVP作为封盖剂存在的情况下,利用氦常压等离子体射流还原HAuCl 4合成金纳米颗粒。首先通过紫外-可见光谱证实了AuNPs的形成。AuNPs的表面等离子体共振(SPR)带在520 ~ 550 nm可见光范围内具有很强的光吸收。用DLS法测定所得纳米颗粒的尺寸,用透射电镜(TEM)观察其形状。TEM图像显示合成了不同形状的aunp(如三角形、六边形、棒状和球形)。研究了等离子体放电时间、前驱体和封盖剂浓度等参数对纳米颗粒尺寸和形状的影响。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Gold Nanoparticles Synthesized by Atmospheric Pressure Plasma Jet
Plasma discharges of different configurations have attracted a lot of attention due to their various applications. In particular, plasma jet in contact with a liquid is a simple and cheap technique for the synthesis of metal nanoparticles. Its main advantage is the variety of species present in the plasma plume which can induce rapid chemical reactions in the solution. Gold nanoparticles have been the focus of many researchers because of their unique physical, optical and chemical properties. They are used in various fields and their characteristic properties depend on their size and morphology. In this work, the synthesis of gold nanoparticles was investigated by reducing HAuCl 4 in the presence of PVP as a capping agent using a Helium atmospheric pressure plasma jet. The formation of AuNPs was firstly confirmed by UV-vis spectra. The surface plasmon resonance (SPR) band of the AuNPs results in a strong optical absorption in the 520-550 nm visible range. The size of the obtained nanoparticles was measured by DLS and their shape was observed by transmission electron microscopy (TEM). The TEM images show that AuNPs of different shapes (e.g. triangle, hexagon, rods, and spherical) were synthesized. The effects of different parameters such as the plasma discharge duration, the precursor and the capping agent concentration on the size and shape of these nanoparticles were studied.
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