L. C. Meher, K. Chandra, N. Sharma, M. Mittal, M. Nasim
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引用次数: 1
摘要
近年来,亚麻荠作为生物燃料的原料引起了人们的研究兴趣。根据EN 14214: 2008, ASTM D 6751-08和IS 15607: 2005规范中提到的测试方法,从芥花油中制备和表征脂肪酸甲酯。两步碱酯交换制得的甲酯含量大于96.5%,单甘油酯、双甘油酯和甘油三酯的含量均在规定范围内。碘值为148 g /100 g,远远高于欧洲标准的期望值;同样,亚麻酸甲酯的含量也很高。理论上计算的十六烷值小于要求值。氧化稳定性较差,而添加100 ppm的合成抗氧化剂邻苯三酚,诱导期为8.1 h。其余燃料参数符合EN 14214: 2008标准。除十六烷值外,其他性能均符合IS 15607: 2005规范。美国规范规定十六烷值最低为47,而亚麻荠甲酯的理论十六烷值略低。十六烷增强剂可用于燃料,以符合美国和印度的规格。
Assessment of Fuel Qualities of Methyl Esters from Camelina sativa Seed Oil for Biofuel Applications
In the recent time, Camelina sativa has attracted research interest as feedstock for biofuels. The fatty acid methyl esters from C. sativa oil was prepared and characterised as per the test methods mentioned in EN 14214: 2008, ASTM D 6751–08 and IS 15607: 2005 specifications. The methyl ester content more than 96.5% was achieved in two-step alkali transesterification, and the percentage of monoglyceride, diglyceride and triglyceride were within the specified limit. The iodine value is 148 g I2/100 g which is quite above the desired value as per the European specification; likewise, the linolenic acid methyl ester content is quite high. The cetane number was calculated theoretically which is less than the required value. The oxidation stability is poor, whereas the addition of synthetic antioxidant that is pyrogallol at 100 ppm attains the induction period of 8.1 h. The rest fuel parameters are in good agreement with EN 14214: 2008 norm. Except cetane number, the other properties are in agreement with the IS 15607: 2005 specification. In case of American specification, the cetane number is specified to be minimum 47, whereas the theoretical cetane number for Camelina methyl ester is slightly lower. Cetane enhancer may be used for the fuel to qualify the American and Indian specifications.