阳离子与冠醚及相关大环络合反应的速率和机理

Cation Binding by Macrocycles Pub Date : 1989-01-23 DOI:10.1201/9781315138893-4

E. Eyring, S. Petrucci

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引用次数: 1

摘要

摘要:综述了非水溶液中大环与金属阳离子络合反应速率的研究进展。特别注意在各种非水溶剂中冠醚的超声吸收和核磁共振研究中产生的不同机理图。展望了络合动力学研究的未来发展方向。大环，冠醚，非水溶液，超声吸收，核磁共振，阳离子络合动力学。

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Rates and Mechanisms of Complexation Reactions of Cations with Crown Ethers and Related Macrocycles

Abstract : Rate studies of complexation reactions of macrocycles reacting with metal cations in nonaqueous solutions are reviewed. Particular attention is given to differing mechanistic pictures arising from ultrasonic absorption and nuclear magnetic resonance studies of crown ethers in a variety of nonaqueous solvents. Future directions of complexation kinetic studies are also considered. Macrocycles, Crown ethers, Nonaqueous solutions, Ultrasonic absorption, Nuclear magnetic resonance, Cation complexation kinetics.

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Cation Binding by Macrocycles

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