固体含量对锂离子电池石墨负极电化学性能的影响

Leyoni Metanencya Butarbutar, S. Priyono
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引用次数: 0

摘要

可充电电池已应用于大多数便携式电子设备。锂离子电池(LIB)作为主要的电源,以其能量密度高、保质期长、操作环保等优势主导着移动设备市场。在可充电锂离子电池中,有四个主要部件,其中一个是阳极。使用的阳极材料是商用石墨。因此,本研究旨在确定固体含量溶剂对电池性能的影响。本研究主要探讨了N, N二甲基乙酰胺(DMAC)的溶剂变化对石墨阳极片特性的影响,以及石墨阳极片固含量的差异对电池性能的影响。通过XRD对所形成的相进行鉴定,通过循环伏安法测试还原氧化反应,通过充放电测试电池容量,通过电化学阻抗谱测试研究电极材料的电化学特性。最佳阳极片材为2.5 mL DMAC溶剂,厚度为0.07 mm,固含量为25%。充放电测试结果表明,第一次充放电比容量为309.33 mAh/g。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Effect of Solid Content in Electrochemical Performance of Graphite Anode of Lithium-ion Batteries
Rechargeable batteries have been implemented in most portable electronic devices. Lithium-ion battery (LIB), as the main power source, dominates the mobile device market due to its high energy density, long shelf life, and environmentally friendly operation. In the rechargeable lithium-ion battery, there are four main components, one of which is the anode. The anode material used is commercial graphite. Thus, this study aims to determine the effect of solid content solvents on battery performance. The main discussion in this study is to analyze the effect of solvent variations of N, N Dimethyl Acetamide (DMAC) on the characteristics of the sheet and the difference in solid content of graphite anode sheets on battery performance. Identification of the formed phase was carried out by XRD, reduction and oxidation reactions by cyclic voltammetry test, battery capacity by charge/discharge test, and study of the electrochemical characteristics of the electrode material by electrochemical impedance spectroscopy test. The best anode sheet is produced by mixing 2.5 mL DMAC solvent at a thickness of 0.07 mm with a solid content of 25%. The results of the charge-discharge test showed a specific capacity of 309.33 mAh/g in the first cycle.
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