黄铁矿接触孪晶。

IF 1.3 3区 化学 Q3 CHEMISTRY, MULTIDISCIPLINARY
Yves Moëlo, Massimo Nespolo, François Farges
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引用次数: 1

摘要

介绍了秘鲁黄铁矿中接触孪晶的两个例子。第一个是在Pasto Bueno矿床,以{120}为主要体型,{111}八面体和{100}立方体为次要体型,呈透镜状。(111)是合成平面,twin操作是该平面内的三个二进制轴⟨110⟩中的任何一个。第二种(未知矿床)呈现八面体{111}和核面体{120}两种形式;孪晶中的两个晶体分别沿[101]和[011]拉长,形成V型轮廓。它是一个反射孪晶,孪晶平面(110)与合成平面重合。这对双胞胎是天生的。另一种接触双胞胎在文献中是已知的,由Gaubert [Bull]报道。Soc。Fr,矿物。Cristallogr。(1928), 51,211 -212]将其描述为尖晶石孪晶,即具有孪晶和组成平面的反射孪晶(111);这里显示它实际上是一个旋转孪生,其中孪生操作是围绕(111)组合平面中⟨211⟩的三个等效方向中的任何一个180°旋转。黄铁矿中尖晶石孪晶的出现以及尖晶石孪晶的不确定性与基于晶体轨道拟对称的结构解释有直接关系。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Pyrite contact twins.

Two examples of contact twins in pyrite from Peru are described. The first one, from Pasto Bueno ore deposit, shows the pyritohedron {120} as principal form, accompanied by the {111} octahedron and {100} cube as secondary forms, giving a lenticular aspect. (111) is the composition plane, and the twin operation is any one of the three binary axes ⟨110⟩ within this plane. The second one (unknown ore deposit) presents two forms, the octahedron {111} and the pyritohedron {120}; the two crystals in the twin are elongated along [101] and [011], respectively, producing a V profile. It is a reflection twin where the twin plane (110) coincides with the composition plane. These twins are by merohedry. Another contact twin is known in the literature, reported by Gaubert [Bull. Soc. Fr. Minéral. Cristallogr. (1928), 51, 211-212] who described it as a spinel twin, i.e. a reflection twin with twin and composition plane (111); here it is shown that it is actually a rotation twin in which the twin operation is a 180° rotation about any of the three equivalent directions ⟨211⟩, contained in the (111) composition plane. The occurrence of these twins as well as the doubtfulness of the spinel twin in pyrite shows a direct relationship with the structural interpretation based on the pseudo-symmetry of the crystallographic orbits.

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来源期刊
Acta crystallographica Section B, Structural science, crystal engineering and materials
Acta crystallographica Section B, Structural science, crystal engineering and materials CHEMISTRY, MULTIDISCIPLINARYCRYSTALLOGRAPH-CRYSTALLOGRAPHY
CiteScore
3.60
自引率
5.30%
发文量
0
期刊介绍: Acta Crystallographica Section B: Structural Science, Crystal Engineering and Materials publishes scientific articles related to the structural science of compounds and materials in the widest sense. Knowledge of the arrangements of atoms, including their temporal variations and dependencies on temperature and pressure, is often the key to understanding physical and chemical phenomena and is crucial for the design of new materials and supramolecular devices. Acta Crystallographica B is the forum for the publication of such contributions. Scientific developments based on experimental studies as well as those based on theoretical approaches, including crystal-structure prediction, structure-property relations and the use of databases of crystal structures, are published.
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