{"title":"Magnetic relaxation in conducting electrolytes","authors":"P.W. Atkins, M.J. Clugston","doi":"10.1016/0001-8716(75)80010-1","DOIUrl":null,"url":null,"abstract":"<div><p>The effect of an electric field on the relaxation of a spin-<span><math><mtext>1</mtext><mtext>2</mtext></math></span> nucleus by a paramagnetic ion in fluid solution is calculated. The model relates to a spin—echo experiment, and depends on inter-ionic magnetic dipole—dipole relaxation. It is shown that under optimum conditions, using electric fields of strength ⪅ 10 MV m<sup>±1</sup>, the value of the nuclear <em>T</em><sub>2</sub> may be changed by about 50%.</p></div>","PeriodicalId":100050,"journal":{"name":"Advances in Molecular Relaxation Processes","volume":"7 1","pages":"Pages 1-11"},"PeriodicalIF":0.0000,"publicationDate":"1975-05-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0001-8716(75)80010-1","citationCount":"3","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Advances in Molecular Relaxation Processes","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/0001871675800101","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 3
Abstract
The effect of an electric field on the relaxation of a spin- nucleus by a paramagnetic ion in fluid solution is calculated. The model relates to a spin—echo experiment, and depends on inter-ionic magnetic dipole—dipole relaxation. It is shown that under optimum conditions, using electric fields of strength ⪅ 10 MV m±1, the value of the nuclear T2 may be changed by about 50%.
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