Ag-integrated mixed metallic Co-Fe-Ni-Mn hydroxide composite as advanced electrode for high-performance hybrid supercapacitors

IF 14 1区 化学 Q1 CHEMISTRY, APPLIED
Anki Reddy Mule, Bhimanaboina Ramulu, Shaik Junied Arbaz, Anand Kurakula, Jae Su Yu
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Abstract

Direct growth of redox-active noble metals and rational design of multifunctional electrochemical active materials play crucial roles in developing novel electrode materials for energy storage devices. In this regard, silver (Ag) has attracted great attention in the design of efficient electrodes. Inspired by the house/building process, which means electing the right land, it lays a strong foundation and building essential columns for a complex structure. Herein, we report the construction of multifaceted heterostructure cobalt-iron hydroxide (CFOH) nanowires (NWs)@nickel cobalt manganese hydroxides and/or hydrate (NCMOH) nanosheets (NSs) on the Ag-deposited nickel foam and carbon cloth (i.e., Ag/NF and Ag/CC) substrates. Moreover, the formation and charge storage mechanism of Ag are described, and these contribute to good conductive and redox chemistry features. The switching architectural integrity of metal and redox materials on metallic frames may significantly boost charge storage and rate performance with noticeable drop in resistance. The as-fabricated Ag@CFOH@NCMOH/NF electrode delivered superior areal capacity value of 2081.9 µA h cm−2 at 5 mA cm−2. Moreover, as-assembled hybrid cell based on NF (HC/NF) device exhibited remarkable areal capacity value of 1.82 mA h cm−2 at 5 mA cm−2 with excellent rate capability of 74.77% even at 70 mA cm−2 Furthermore, HC/NF device achieved maximum energy and power densities of 1.39 mW h cm−2 and 42.35 mW cm−2, respectively. To verify practical applicability, both devices were also tested to serve as a self-charging station for various portable electronic devices.

Abstract Image

银集成混合金属Co-Fe-Ni-Mn氢氧化物复合材料作为高性能混合超级电容器的先进电极
氧化还原活性贵金属的直接生长和多功能电化学活性材料的合理设计对于开发新型储能电极材料至关重要。在这方面,银(Ag)在高效电极的设计中引起了极大的关注。受房屋/建筑过程的启发,这意味着选择合适的土地,它为复杂的结构奠定了坚实的基础,并建造了重要的柱子。在此,我们报道了在Ag沉积的泡沫镍和碳布(即Ag/NF和Ag/CC)衬底上构建多层异质结构钴-氢氧化铁(coh)纳米线(NWs)@镍-钴-锰-氢氧化物和/或水合物(NCMOH)纳米片(NSs)。此外,还描述了银的形成和电荷储存机制,这有助于银具有良好的导电性和氧化还原化学特性。金属和氧化还原材料在金属框架上的开关结构完整性可以显著提高电荷存储和速率性能,同时显著降低电阻。制备的Ag@CFOH@NCMOH/NF电极在5ma cm - 2时具有2081.9µA h cm - 2的优越面积容量值。此外,基于NF (HC/NF)装置组装的混合电池在5 mA cm - 2条件下的面积容量值为1.82 mA h cm - 2,即使在70 mA cm - 2条件下也具有74.77%的优良倍率能力,并且HC/NF装置的最大能量密度和功率密度分别为1.39 mW h cm - 2和42.35 mW cm - 2。为了验证其实用性,我们还测试了这两个装置作为各种便携式电子设备的自充电站。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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来源期刊
CiteScore
23.60
自引率
0.00%
发文量
2875
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