The influence of moisture content on polycyclic aromatic hydrocarbons emission during rice straw burning

Takashi Korenaga , Xiaoxing Liu , Zuyun Huang
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引用次数: 73

Abstract

Open burning was carried out for rice straw samples with moisture contents of 0%, 5%, 10%, 15%, 20%, 25%, and 30%, respectively. The 10 EPA priority polycyclic aromatic hydrocarbons (PAHs) compounds plus naphthacene and perylene were analyzed by means of GC/MS. Total particulate PAHs emission varied between 1 and 38 mg/kg for12 species-specific PAHs. Experimental results showed that water has a depression effect on PAHs emission during rice straw burning. The lowest emission of total particulate PAHs was obtained when rice straw with 15% moisture content was burned. 11 species-specific PAHs showed the lowest emissions within 10–20% moisture content exclusive of naphthacene. In addition, higher emission was observed for intermediate molecular weight compounds such as fluoranthene, pyrene, benz[a]anthracene and chrysene, and relatively lower emission for heavier molecular weight compounds such as perylene, benzo[a]pyrene and dibenz[ah]anthracene.

稻秆燃烧过程中水分含量对多环芳烃排放的影响
对含水率分别为0%、5%、10%、15%、20%、25%和30%的稻草样品进行露天焚烧。采用GC/MS分析了10种EPA优选的多环芳烃(PAHs)及萘和苝化合物。12种物种特异性多环芳烃的总颗粒排放在1至38 mg/kg之间。实验结果表明,水对秸秆燃烧过程中多环芳烃的释放有抑制作用。当稻秆含水率为15%时,总颗粒多环芳烃的排放量最低。除萘外,在水分含量为10 ~ 20%的范围内,11种特定种的多环芳烃的排放量最低。此外,中等分子量的化合物如氟蒽、芘、苯并[a]芘和蒽的发射量较高,而较重分子量的化合物如苝、苯并[a]芘和二苯并[ah]蒽的发射量相对较低。
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