Transition metal oxides as catalysts for the selective reduction of nitrobenzene

Q4 Chemical Engineering

分子催化 Pub Date : 1994-10-27 DOI:10.1016/0304-5102(94)00121-9

A. Maltha, S.C. van Wermeskerken, B. Brunet, V. Ponec

引用次数: 11

Abstract

The activity of various 3d, 4d and 5d transition metal oxides in the selective reduction of nitrobenzene to nitrosobenzene has been investigated. An attempt has been made to find a correlation between these activities and several properties of the oxides investigated, such as their place in the Periodic Table, structure, reducibility, heat of formation and surface metal—oxygen bond strength. A weak volcano-shape correlation can be seen with the heat of formation and the surface metal—oxygen bond strength.

查看原文本刊更多论文

过渡金属氧化物作为硝基苯选择性还原催化剂的研究

研究了各种3d、4d和5d过渡金属氧化物在硝基苯选择性还原为亚硝基苯中的活性。人们试图找出这些活性与所研究的氧化物的一些性质之间的关系，如它们在元素周期表中的位置、结构、还原性、生成热和表面金属-氧键强度。形成热和表面金属-氧结合强度与火山形状的相关性较弱。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

求助全文

约1分钟内获得全文求助全文

来源期刊

分子催化 Chemical Engineering-Catalysis

CiteScore

1.50

自引率

0.00%

发文量

2959

期刊介绍： Journal of Molecular Catalysis (China) is a bimonthly journal, founded in 1987. It is a bimonthly journal, founded in 1987, sponsored by Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, under the supervision of Chinese Academy of Sciences, and published by Science Publishing House, which is a scholarly journal openly circulated both at home and abroad. The journal mainly reports the latest progress and research results on molecular catalysis. It contains academic papers, research briefs, research reports and progress reviews. The content focuses on coordination catalysis, enzyme catalysis, light-ribbed catalysis, stereochemistry in catalysis, catalytic reaction mechanism and kinetics, the study of catalyst surface states and the application of quantum chemistry in catalysis. We also provide contributions on the activation, deactivation and regeneration of homogeneous catalysts, solidified homogeneous catalysts and solidified enzyme catalysts in industrial catalytic processes, as well as on the optimisation and characterisation of catalysts for new catalytic processes. The main target readers are scientists and postgraduates working in catalysis in research institutes, industrial and mining enterprises, as well as teachers and students of chemistry and chemical engineering departments in colleges and universities. Contributions from related professionals are welcome.