An investigation on Portland cement replaced by high-volume GGBS pastes modified with micro-sized metakaolin subjected to elevated temperatures

Alaa M. Rashad, Dina M. Sadek
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引用次数: 75

Abstract

Ground granulated blast-furnace slag (designated as GGBS) has been utilized as building material due to the environmental, economic and technical benefits. In this study, the possibility of improving compressive strength of high-volume GGBS (HVS) paste before and after being exposed to elevated temperatures using metakaolin (MK) in micro-size (mMK) has been investigated. Portland cement (PC) has been partially substituted with GGBS at level of 70%, by weight, to produce HVS paste. Afterword, GGBS was partially substituted with mMK at levels ranging from 2% to 10% with an increment of 2%, by weight. After curing, the specimens were subjected to elevated temperatures ranging from 400 °C to 1000 °C with an interval of 200 °C for 2 h. Weight and compressive strength before and after being exposed to elevated temperatures have been thoroughly explored. The various decomposition phases formed were identified using X-ray diffraction (XRD) and thermogravimetric (TGA) analyses. The morphology of the formed hydrates was studied using scanning electron microscopy (SEM). The results showed that the compressive strength before and after being exposed to elevated temperatures increased with increasing mMK content. For all mixtures, the residual compressive strength at 400 °C reached its maximum peak value.

高温条件下微偏高岭土改性大体积GGBS膏体替代硅酸盐水泥的研究
粉状高炉矿渣具有良好的环境、经济和技术效益,已被广泛应用于建筑材料中。在本研究中,研究了微尺寸偏高岭土(MK)在高温暴露前后提高高体积GGBS (HVS)膏体抗压强度的可能性。波特兰水泥(PC)已部分被GGBS取代,以70%的重量水平生产HVS膏体。最后,GGBS部分被mMK取代,其含量在2%到10%之间,按重量增加2%。固化后,试样进行400 ~ 1000℃的高温处理,间隔时间为200℃,持续2 h。对高温处理前后的重量和抗压强度进行了全面的研究。通过x射线衍射(XRD)和热重(TGA)分析确定了所形成的各种分解相。利用扫描电子显微镜(SEM)研究了形成的水合物的形貌。结果表明,随着mMK含量的增加,高温处理前后材料的抗压强度均呈上升趋势。所有混合物的残余抗压强度在400℃时均达到最大值。
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