Assessment of Polybrominated Diphenyl Ethers (PBDEs) Level and Physico-Chemical Characteristics of Water and Sediment of Gulf of Guinea

O. Oladejo, A. O. Nubi, R. Adesina, O. O. Oyatola, B. O. Bassey
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Abstract

The Lagos lagoon is the largest of the four lagoon systems of the Gulf of Guinea coast. This aquatic resource of multiple usages receives diverse organic and inorganic materials from domestic, industrial, emission, and thermal sources. The levels of Polybrominateddiphenyl ethers (PBDEs) were assessed to ascertain the pollution status of surface water and sediment within this lagoon system. Four stations were sampled for PBDEs analysis, and ranged for surface water physicochemical parameters are (27.93 to 28.50 ⁰C), (115.00 to 2152.70 µS/cm), (2.00 to 2.80 mg/L), (6.45 to 7.63), (25.02 to 84.60 NTU), (226.30 to 3999.00 mg/L), for temperature, electrical conductivity, dissolved oxygen, pH, turbidity, and total dissolved solids respectively. While the Total Organic Carbon (TOC) in sampled sediment ranged from 0.5 to 5.71 mg/L., the total concentrations of PBDEs in sediments ranged from 31.6 to 47.5 µg/Kg. Whereas the BDEs concentration in water ranged from 3.7 to 10.5 pg/L, total PBDE concentration of individual congener for water ranged from approximately 0.8 to 12.5 pg/L. The BDE 28 predominates across the locations followed by BDE 99. Impact of PBDEs concentration in the marine environment was evident within the study area.
几内亚湾水体和沉积物中多溴联苯醚(PBDEs)含量及理化特征评价
拉各斯泻湖是几内亚湾沿岸四个泻湖系统中最大的一个。这种多种用途的水生资源接收来自家庭、工业、排放和热源的各种有机和无机材料。评估了多溴联苯醚(PBDEs)的水平,以确定该泻湖系统内地表水和沉积物的污染状况。采样四个站点进行多溴二苯醚分析,地表水的物理化学参数范围分别为(27.93至28.50⁰C),(115.00至2152.70µS/cm),(2.00至2.80 mg/L),(6.45至7.63),(25.02至84.60 NTU),(226.30至399.00 mg/L),分别为温度,电导率,溶解氧,pH,浊度和总溶解固体。总有机碳(TOC)含量在0.5 ~ 5.71 mg/L之间。,沉积物中多溴二苯醚的总浓度在31.6 ~ 47.5µg/Kg之间。水中多溴二苯醚的浓度范围为3.7至10.5 pg/L,而水中单个同系物的总多溴二苯醚浓度范围约为0.8至12.5 pg/L。BDE 28在各地区占主导地位,其次是BDE 99。多溴二苯醚浓度对研究区内海洋环境的影响是明显的。
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