CHEMIOMETRIC STUDY ON THE INFLUENCE OF CAROTENOIDS AND SATURATED FATTY ACIDS IN BIODIESEL STORAGE STABILITY

K. S. Figueredo, C. P. Prados, L. V. Milhomem, A. R. Silva
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Abstract

Biodiesel is a fuel derived from renewable raw materials with the potential to change the world's energy matrix, and reduce the damage caused by fossil fuels to the environment and human health. The disadvantage of biodiesel is its low oxidative stability which affects its storage time. In this study, experimental biodiesel blends were used to identify the influences of carotenoid and free fatty acid contents on storage stability by using UV-VIS spectroscopy. Binary biodiesel blends were prepared blending buriti biodiesel contents ranging from 30% (v/v), 60% (v/v), and 90% (v/v) with soybean, sunflower, and beef tallow biodiesel. The blends were stored up to 45 days to compare the oxidative stabilities. The binary biodiesel blend composed by 90% buriti biodiesel and 10% beef tallow one presented the highest oxidative stability during the evaluated storage time.
类胡萝卜素和饱和脂肪酸对生物柴油贮存稳定性影响的化学计量学研究
生物柴油是一种从可再生原料中提取的燃料,有可能改变世界的能源矩阵,并减少化石燃料对环境和人类健康造成的损害。生物柴油的缺点是氧化稳定性低,影响了其贮存时间。本研究以实验生物柴油混合物为研究对象,利用紫外-可见光谱法研究了类胡萝卜素和游离脂肪酸含量对生物柴油贮存稳定性的影响。将含有30% (v/v)、60% (v/v)和90% (v/v)的buriti生物柴油与大豆、向日葵和牛脂生物柴油共混制备二元生物柴油混合物。将混合物保存45天,以比较其氧化稳定性。由90% buriti生物柴油和10%牛油生物柴油组成的二元生物柴油混合物在评估的储存时间内表现出最高的氧化稳定性。
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