Study of Alternative Methods for Preparing the Pitch Binder for the Anode Paste

E. N. Marakushina, V. Frizorger, D. Lazarev, Mikhail I. Krak, P. N. Kuznetsov, F. A. Buryukin
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Abstract

800x600 Aluminium smelting industry is the biggest consumer of coal tar pitch, but the use of pitch causes numerous problems because of some economic and environmental factors. Russia’s growing deficit is covered by import deliveries, which cannot guarantee a secure future. At the same time stricter environmental sanctions related to the use of coal tar pitch as a source of cancer-inducing emissions, are supporting the search for alternative raw materials and the development of new pitch binder production techniques. Given that the known reserves of bituminous coal will be sufficient to last for 230 years at the current production rates as opposed to the oil reserves that will be enough for 40 years only, it becomes obvious that the development of a pitch binder production technique based on thermochemical processing of coals is a promising direction to follow. Investigations were carried out to dissolve coals thermo-chemically in various organic solvents at varying levels of temperature, pressure, and reaction times. It was shown how mechanic activation and ultrasonic exposure affect the degree of organic coal mass extraction. The methods of vacuum and atmospheric distillation were used to produce pitch products from coal extracts. It was demonstrated that the use of coking additives, including nano-modified carbon, helps improve the application properties of pitch products. Large-sized samples of coal tar pitch were used to produce trial lots of anode paste for Soederberg anodes. Normal 0 false false false RU X-NONE X-NONE /* Style Definitions */ table.MsoNormalTable {mso-style-name:"Обычная таблица"; mso-tstyle-rowband-size:0; mso-tstyle-colband-size:0; mso-style-noshow:yes; mso-style-priority:99; mso-style-parent:""; mso-padding-alt:0cm 5.4pt 0cm 5.4pt; mso-para-margin:0cm; mso-para-margin-bottom:.0001pt; mso-pagination:widow-orphan; font-size:10.0pt; font-family:"Calibri","sans-serif";}
制备阳极浆料沥青粘结剂的替代方法研究
铝冶炼行业是煤沥青的最大消费国,但由于一些经济和环境因素,沥青的使用产生了许多问题。俄罗斯日益增长的赤字是靠进口来弥补的,这并不能保证一个安全的未来。与此同时,对煤焦油沥青作为致癌排放物的使用实施了更严格的环境制裁,支持寻找替代原料和开发新的沥青粘合剂生产技术。鉴于烟煤的已知储量以目前的生产速度将足以使用230年,而石油储量仅够使用40年,因此,基于煤的热化学处理的沥青粘合剂生产技术的发展显然是一个有前途的方向。研究了在不同温度、压力和反应时间下,用热化学方法将煤溶解在各种有机溶剂中。研究了机械活化和超声暴露对有机煤体抽提程度的影响。采用真空蒸馏法和常压蒸馏法对煤抽提物进行了沥青产品的制备。实验结果表明,使用纳米改性碳等焦化添加剂有助于提高沥青制品的应用性能。采用大尺寸煤焦油沥青样品制备Soederberg阳极阳极膏。正常0 false false false RU X-NONE X-NONE /* Style Definitions */表。MsoNormalTable {mso-style-name:“Обычнаятаблица”;mso-tstyle-rowband-size: 0;mso-tstyle-colband-size: 0;mso-style-noshow:是的;mso-style-priority: 99;mso-style-parent:“”;Mso-padding-alt:0cm 5.4pt;mso-para-margin: 0厘米;mso-para-margin-bottom: .0001pt;mso-pagination: widow-orphan;字体大小:10.0分;“无衬线字体类型:“Calibri”;}
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