Gold and silver oxide conducting nanocomposite cathode for glucose biofuel cell

Saikat Banerjee, Mathew L. Nguyen, G. Slaughter
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Abstract

A glucose biofuel cell on a flexible bacterial nanocellulose film was prepared. The bioelectrodes were printed using gold ink as the conductive material. The anode was modified with colloidal platinum for the oxidation of glucose. The cathode was modified with a nanocomposite comprising gold nanoparticles (AuNPs) and silver oxide (Ag2O) nanoparticles. The cathode was characterized via cyclic voltammetry (CV), electrochemical impedance spectroscopy (EIS), and UV spectroscopy techniques. The assembled biofuel cell generated a maximum open circuit voltage (Voc) of 0.485 V, short circuit current (Isc) of 0.352 mA/cm2, and a maximum peak power density (Pmax) of 0.032 mW/cm2 when operating in 30 mM concentration. This system showed a stable and linear performance with a linear range of 1 mM to 30 mM glucose. The gold printed electrode process is applicable to the development of wearable and implantable abiotic biofuel cell.
葡萄糖生物燃料电池用氧化金银导电纳米复合阴极
在柔性细菌纳米纤维素薄膜上制备了葡萄糖生物燃料电池。生物电极采用金墨水作为导电材料进行印刷。用胶体铂修饰阳极用于葡萄糖的氧化。用纳米金纳米粒子(AuNPs)和氧化银纳米粒子(Ag2O)修饰阴极。通过循环伏安法(CV)、电化学阻抗谱(EIS)和紫外光谱技术对阴极进行了表征。组装的生物燃料电池在30 mM浓度下工作时,最大开路电压(Voc)为0.485 V,短路电流(Isc)为0.352 mA/cm2,最大峰值功率密度(Pmax)为0.032 mW/cm2。该系统表现出稳定的线性性能,线性范围为1 ~ 30 mM葡萄糖。金印刷电极工艺适用于可穿戴和可植入的非生物生物燃料电池的开发。
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