Preparation Pilocarpine Hydrochloride Selective Electrodes

A. M. Abass
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引用次数: 3

Abstract

New eight selective electrodes of pilocarpine hydrochloride deepened on complexes of (PCH) -molybdophosphoric acid and (PCH) – phosphotungstate were prepared with varied plasticizers. Electrode with complex (DBPH-MP) was used as an active material, gave linear range from 5.0×10-2 to 6.0×10-5 M, and slope was 62.01 mV/decade, with detection limit was 2.0×10-5M, lifetime was near to 60 days. Electrode,s membrane made with active material (DBP-MP), showed concentration range was 2.1×10-3-6.3×10-5M, the slope was near to 52.34 mV/decade. Detection limit was 1.0×10-5M, 55 days was the life time of this electrode. The parameters of electrode deepened on (DBPH-PT), concentration range was from 5.0×10-2 to 6.5×10-5 M with slope 50.41 mV/decade, 2.2×10-5 M was the detection limit.Life time was determined around to 52 days.
盐酸匹洛卡品选择性电极的制备
用不同的增塑剂制备了盐酸匹洛卡品在(PCH) -钼磷酸和(PCH) -磷钨酸盐络合物上加深的新型8种选择性电极。以配合物电极(DBPH-MP)为活性材料,线性范围为5.0×10-2 ~ 6.0×10-5 M,斜率为62.01 mV/ 10年,检出限为2.0×10-5M,寿命接近60天。用活性物质(DBP-MP)制备的电极膜的浓度范围为2.1×10-3-6.3×10-5M,斜率接近52.34 mV/decade。检出限为1.0×10-5M,电极寿命为55天。电极参数加深(DBPH-PT),浓度范围为5.0×10-2 ~ 6.5×10-5 M,斜率为50.41 mV/ 10年,2.2×10-5 M为检出限。寿命约为52天。
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