Preparation of Magnesium Hydroxide from Magnesite by means of Mechanochemical Treatment and its Reactivity.

Qiwu Zhang, F. Saito, M. Hanada
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引用次数: 1

Abstract

Mechanochemical process for producing Mg (OH) 2 from magnesite (MgCO3) without heat treatment has been developed. This process is composed of two steps: The first step is to produce Mg (OH) 2 and Na2CO3 mechanochemically by dry grinding the mixture of magnesite and solid NaOH powders in a mill. The reaction between the two starting samples proceeds as the grinding progresses. The second step is to separate Na2CO3 from the insoluble products in the ground mixture by washing with water. Reactivity of the insoluble products against H2SO4 solution is improved with increasing the grinding time, and levels off in the prolonged grinding. The reactivity of the insoluble products prepared from the mixtures ground for 0 minutes or more is much higher than that of magnesite powder. The separated Na2CO3 can be reused for appropriate purposes
菱镁矿机械化学处理制备氢氧化镁及其反应性。
研究了以菱镁矿(MgCO3)为原料,不经热处理机械化学制取Mg (OH) 2的工艺。该工艺由两步组成:第一步是将菱镁矿和固体氢氧化钠粉末的混合物在磨机中干磨,机械化学法生产Mg (OH) 2和Na2CO3。随着磨矿的进行,两种起始试样之间的反应也在进行。第二步是用水洗涤将Na2CO3从研磨混合物中的不溶性产物中分离出来。不溶性产物对H2SO4溶液的反应性随磨矿时间的延长而提高,随磨矿时间的延长而趋于平稳。混合料研磨0分钟以上制备的不溶性产物的反应活性远高于菱镁矿粉。分离后的Na2CO3可用于适当的用途
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