Synthesis of nanoporous functional materials for the chemical industry

A. Memetova, A. Zelenin, N. Memetov, T. Pasko, A. Gerasimova, D. Tarov
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Abstract

In this study, we synthesized samples of nanoporous carbon materials (NCM) from polymer raw materials. The influence of the conditions of the synthesis process (the mass ratio of the activating agent to the precursor) on the structure of the obtained samples has been studied. Varying the mass ratio of the activating agent to the precursor made it possible to obtain microporous, micromesoporous, and mesoporous carbon materials. Methane adsorption has been researched in a wide pressure range. The highest adsorption of methane, equal to ≈ 20 mmol/g at 100 bar and 298 K, is achieved on a sample with a ratio of the activating agent KOH to carbonized precursor 6:1 (6NCM).
化工用纳米多孔功能材料的合成
在本研究中,我们以高分子为原料合成了纳米多孔碳材料(NCM)。研究了合成工艺条件(活化剂与前驱体的质量比)对所得样品结构的影响。改变活化剂与前驱体的质量比,可以获得微孔、微介孔和介孔碳材料。在较宽的压力范围内对甲烷吸附进行了研究。当活化剂KOH与炭化前驱体的比例为6:1 (6NCM)时,在100 bar和298 K下,甲烷的最高吸附量为≈20 mmol/g。
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