19th century ornamented metal trays from Greece and Turkey: metallurgy and provenance

Despoina Kotzamani, V. Kantarelou, I. Karatasios, Marianna Zacharia
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Abstract

ABSTRACT Twelve ‘Japanned’ metal trays from Greece and Turkey, dated in the 19th century, were subjected to macroscopic and microscopic examination (stereoscopy, metallography, scanning electron microscopy) as well as to XRF and SEM-EDX analysis. The trays represent two stylistic types made of wrought iron either tin-plated or protected with a primer. Two were manufactured by forging while the rest were made by rolling prior to die forming with drop hammers or machine presses. Wrought iron was produced indirectly from cast iron with fossil fuels. Only in one case charcοal fuel was implied. Most pure iron was recognized for four trays dated at the end of the 19th century. Three of them also revealed the deliberate incorporation of metallic manganese while one of them was found to be alloyed. The other metals used such as copper, brass, silver and tin as also the methods applied, seem to follow the industrial evolution of the iron substrate but more analysis is required. As regards origin, the metallurgical results, even limited, combined with historical information, indicated that the metals/techniques used, were probably originally produced in west Europe although the supply of materials could have depended on different sources.
来自希腊和土耳其的19世纪装饰金属托盘:冶金和来源
来自希腊和土耳其的12个19世纪的“日本”金属托盘进行了宏观和微观检查(立体、金相、扫描电子显微镜)以及XRF和SEM-EDX分析。托盘代表两种风格类型的锻铁要么镀锡或保护底漆。其中两种是通过锻造制造的,而其余的则是在用落锤或机器压力机模压成型之前通过轧制制造的。熟铁是用化石燃料间接从铸铁中生产出来的。只有在一个案例中使用了碳ο燃料。最纯的铁被认为是19世纪末的四个托盘。其中三颗还显示故意加入了金属锰,而其中一颗被发现是合金。所用的其他金属,如铜、黄铜、银和锡,以及所采用的方法,似乎遵循铁衬底的工业演变,但需要更多的分析。关于起源,冶金结果,即使是有限的,结合历史资料,表明所使用的金属/技术,最初可能是在西欧生产的,尽管材料的供应可能依赖于不同的来源。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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