Fabrication of Superhydrophobic Self-Cleaning Coatings by Facile Method: Stable after Exposure to Low Temperatures and UV Light

O. Toktarbaiuly, A. Kurbanova, O. Ualibek, A. Seralin, T. Zhunussova, G. Sugurbekova, N. Nuraje
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Abstract

Self-cleaning hydrophobic surfaces attracted public attention last few decades after discovering of lotus ef-fect. Ability of lotus leaves to keep cleanness in relatively dirty places and to clean up itself during rains di-rected to the development of novel materials and surface structure modification. The surface with such smart properties may have potential in cost-effectiveness in case of application it in skyscrapers, high buildings, etc. Two main criteria for the surface to express hydrophobic behavior are roughness and low surface energy of the coating material. In this study, superhydrophobic self-cleaning coatings were prepared by simple, facile and cheap method using easily available materials such as polydimethylsiloxane (PDMS) and TiO2 nanopar-ticles and fully characterized for direct usage. PDMS is a bonding layer and TiO2 nanoparticles are a rein-forced composite to form roughness, which shows superhydrophobicity. Characterizations showed that the as prepared superhydrophobic coating has a water contact angle up to 165.5°, with sliding angle of less than 5º. Also self-cleaning and surface microfluidic properties have been studied. The superhydrophobic properties of these coatings do not change even after exposure its surface to low temperatures and UV light. SEM images confirm rough structure of obtained surface on glass and sand grains
易溶法制备超疏水自清洁涂层:低温和紫外线稳定
近几十年来,自洁疏水表面在莲花效应发现后引起了人们的广泛关注。荷叶在相对肮脏的地方保持清洁的能力,以及在下雨时自我清理的能力,直接导致了新材料的发展和表面结构的改变。具有这种智能特性的表面在应用于摩天大楼、高层建筑等方面可能具有潜在的成本效益。表面表现疏水行为的两个主要标准是涂层材料的粗糙度和低表面能。本研究利用聚二甲基硅氧烷(PDMS)和TiO2纳米颗粒等易得材料,通过简单、便捷、廉价的方法制备了超疏水自清洁涂层,并充分表征了其可直接使用的特性。PDMS是一种键合层,TiO2纳米粒子是一种增强复合材料,形成粗糙度,表现出超疏水性。表征结果表明,制备的超疏水涂层的水接触角可达165.5°,滑动角小于5º。研究了自洁性和表面微流控特性。这些涂层的超疏水性即使暴露在低温和紫外线下也不会改变。扫描电镜图像证实了玻璃和砂粒表面的粗糙结构
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