Biosorption of Methylene Blue by Activated Carbon from Sugarcane Waste (ACSW)

H. Iyabu, Wiwin Rewini Kunusa, Ishak Isa, Doly Prima Silaban
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Abstract

This study was aimed to produce and characterized activated carbon from sugarcane bagasse by physical and chemical activation. Physical activation was performed by carbonation process in temperatures 4500C and 6500C. While chemical activationusedH3PO4 10%, FeCl3 10% and KMnO4 10% as activator. The results showed that total yield (%) 49.8396 - 80.635; pH 4.0-7.9; ash content (g) 0.3338-0.8820; adsorption capacity of iod (%) 93.92-99.20. Morphological structure, functional group and Crystal structure was studied by using SEM analysis, FT-IR and XRD Difragtogram respectively.Adsorption capacity(%) of methylene blue 1.5 ppm and 2.5 ppm using UV-VIS Spectrophotometer produces; for H3PO4activatorat 450℃ = 99.24 and ND;at 600℃ = ND and 99.24. FeCl3 activator at 450℃ = 93.8 and 28.68; At 600℃ = ND and 99.24. KMnO4 activator at 450℃ = 61.24 and 65.12; At 600℃ = 39.4 and 53.79.
活性炭对蔗渣亚甲基蓝的生物吸附研究
以甘蔗渣为原料,采用物理活化和化学活化法制备活性炭,并对其进行了表征。在4500C和6500C的温度下通过碳化法进行物理活化。化学活化采用10%的h3po4、10%的FeCl3和10%的KMnO4作为活化剂。结果表明:总收率(%)49.8396 ~ 80.635;pH值4.0 - -7.9;灰分(g) 0.3338 ~ 0.8820;碘(%)吸附量93.92 ~ 99.20。采用扫描电镜(SEM)、红外光谱(FT-IR)和x射线衍射(XRD)等分析方法研究了材料的形态结构、官能团和晶体结构。用紫外-可见分光光度计对亚甲基蓝1.5 ppm和2.5 ppm的吸附量(%)测定;h3po4活化剂450℃= 99.24,ND; 600℃= ND, 99.24。FeCl3活化剂450℃= 93.8和28.68;在600℃= ND和99.24。450℃时KMnO4活化剂= 61.24和65.12;600℃= 39.4和53.79。
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