Research on the Characterization of Ag+Cu+B83 Composite Coatings on the Surface of Tin Bronze by Electro-spark Deposition

Zhang Zhengchuan, V. Tarelnyk, I. Konoplianchenko, Liu Guanjun, Du Xin, Y. Hua
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Abstract

The composite coatings of the tin bronze surface that was formed by alternately Electro-spark deposition (ESD) applying the soft anti-friction material of silver, copper, and babbit B83. The analysis of deposition on mass, roughness, cross-section morphology, surface morphology, thickness, elemental composition, and microhardness of the coatings were investigated by electronic scales, 3D optical profilometers, metallographic microscope, scanning electron microscopy (SEM), energy dispersion spectrum (EDS) and Vickers microhardness tester. The results show that the optimal process parameters of ESD are as follows: voltage is 60V/60V/30V, capacitance is 150μF/150μF/90μF and productive capacity is 3(min/cm2) /3(min/cm2) /4(min/cm2), respectively. Under the optimal parameters, the unit coating mass of the substrate is 54.4 mg/cm2, and the surface roughness of the coating is 32.3μm. The coatings are dense, metallurgical fusion with the substrate, and under the optimal parameters, the thickness of the coatings is about 100 μm. The elemental composition of the three characteristic regions (smooth surface, rough surface, and pore) on the surface of the composite coating varies significantly due to the different production modes. The hardness distribution from the coating surface to the substrate increases first, then decreases, and then increases gradually. The surface microhardness of the composite coatings is 29 HV0.01, which is about 82% lower than that of the tin bronze substrate (161 HV0.01).
电火花沉积镀锡青铜表面Ag+Cu+B83复合镀层的研究
镀银、镀铜、镀巴氏合金B83等软抗摩擦材料,通过静电放电沉积(ESD)在锡青铜表面形成复合镀层。采用电子衡、三维光学轮廓仪、金相显微镜、扫描电镜(SEM)、能谱仪(EDS)和维氏显微硬度计对镀层的质量、粗糙度、截面形貌、表面形貌、厚度、元素组成和显微硬度进行了分析。结果表明,ESD的最佳工艺参数为:电压为60V/60V/30V,电容为150μF/150μF/90μF,生产能力为3(min/cm2) /3(min/cm2) /4(min/cm2)。在最优参数下,基底的单位涂层质量为54.4 mg/cm2,涂层表面粗糙度为32.3μm。镀层致密,与基体有冶金熔接,在最佳参数下,镀层厚度约为100 μm。由于不同的生产方式,复合涂层表面的三个特征区域(光滑表面、粗糙表面和孔隙)的元素组成差异较大。从涂层表面到基体的硬度分布先增大后减小,再逐渐增大。复合镀层的表面显微硬度为29 HV0.01,比锡青铜基体(161 HV0.01)低约82%。
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