Research on Adsorption of Chromium (VI) from Wastewater by Anion Exchange Resin

J. Rashid, M. Barakat, M. Alghamdi
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Abstract

The use of a strong anion exchange resin (Spectra/Gel IE 1x8) as an adsorbent for the efficient removal of Cr(VI) ions from synthetic wastewater solutions has been studied.Initial Cr(VI) ions concentrations in batch tests ranged from 25 to 300 mg/L. Various factors impacting Cr(VI) adsorption, such as solution pH, Cr(VI) and adsorbent concentrations, and contact time, were investigated. The results showed that Cr(VI) was successfully retained by the resin. For initial Cr(VI) concentrations up to 100 mg/L, equilibrium was reached in 30 minutes. The equilibrium data for adsorption of Cr(VI) was fitted with both Langmuir and Freundlich isotherms, however, the Langmuir isotherm model was shown to be more suitable for Cr(VI) adsorption, with a maximum adsorption capacity of 173.8 mg/g. The adsorption process followed second order kinetics. After three regeneration cycles, the resin was regenerated with 4M NaOH as an eluent and retained a Cr(VI) adsorption effectiveness of more than 83%.
阴离子交换树脂吸附废水中六价铬的研究
研究了使用强阴离子交换树脂(Spectra/Gel IE 1x8)作为吸附剂,有效去除合成废水溶液中的Cr(VI)离子。批量试验中初始Cr(VI)离子浓度为25 ~ 300 mg/L。考察了溶液pH、吸附剂浓度、接触时间等因素对Cr(VI)吸附性能的影响。结果表明,该树脂成功地保留了Cr(VI)。初始Cr(VI)浓度高达100 mg/L时,30分钟内达到平衡。吸附Cr(VI)的平衡数据同时符合Langmuir和Freundlich等温线,但Langmuir等温线模型更适合Cr(VI)的吸附,其最大吸附量为173.8 mg/g。吸附过程服从二级动力学。经过3次再生循环后,以4M NaOH为洗脱剂再生树脂,树脂对Cr(VI)的吸附率保持在83%以上。
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